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(E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate
In the title compound, C(12)H(12)N(2)O(3)S·2C(2)H(6)OS, the acetic acid and cinnamoyl groups adopt Z and E configurations, respectively, with respect to the thio group about the C—N bonds. The components of the asymmetric unit are connected by N—H⋯O and O—H⋯O hydrogen bonds and in the crystal weak i...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201284/ https://www.ncbi.nlm.nih.gov/pubmed/22058788 http://dx.doi.org/10.1107/S1600536811036750 |
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author | Hassan, Ibrahim N. Wan Daud, Wan Ramli Yamin, Bohari M. Kassim, Mohammad B. |
author_facet | Hassan, Ibrahim N. Wan Daud, Wan Ramli Yamin, Bohari M. Kassim, Mohammad B. |
author_sort | Hassan, Ibrahim N. |
collection | PubMed |
description | In the title compound, C(12)H(12)N(2)O(3)S·2C(2)H(6)OS, the acetic acid and cinnamoyl groups adopt Z and E configurations, respectively, with respect to the thio group about the C—N bonds. The components of the asymmetric unit are connected by N—H⋯O and O—H⋯O hydrogen bonds and in the crystal weak intermolecular C—H⋯O and C—H⋯S hydrogen bonds further connect the components into chains along the b axis. In the main molecule, an intramolecular N—H⋯O hydrogen bond is also present. |
format | Online Article Text |
id | pubmed-3201284 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32012842011-11-06 (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate Hassan, Ibrahim N. Wan Daud, Wan Ramli Yamin, Bohari M. Kassim, Mohammad B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(12)N(2)O(3)S·2C(2)H(6)OS, the acetic acid and cinnamoyl groups adopt Z and E configurations, respectively, with respect to the thio group about the C—N bonds. The components of the asymmetric unit are connected by N—H⋯O and O—H⋯O hydrogen bonds and in the crystal weak intermolecular C—H⋯O and C—H⋯S hydrogen bonds further connect the components into chains along the b axis. In the main molecule, an intramolecular N—H⋯O hydrogen bond is also present. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201284/ /pubmed/22058788 http://dx.doi.org/10.1107/S1600536811036750 Text en © Hassan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Hassan, Ibrahim N. Wan Daud, Wan Ramli Yamin, Bohari M. Kassim, Mohammad B. (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
title | (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
title_full | (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
title_fullStr | (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
title_full_unstemmed | (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
title_short | (E)-2-(3-Cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
title_sort | (e)-2-(3-cinnamoylthioureido)acetic acid dimethyl sulfoxide disolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201284/ https://www.ncbi.nlm.nih.gov/pubmed/22058788 http://dx.doi.org/10.1107/S1600536811036750 |
work_keys_str_mv | AT hassanibrahimn e23cinnamoylthioureidoaceticaciddimethylsulfoxidedisolvate AT wandaudwanramli e23cinnamoylthioureidoaceticaciddimethylsulfoxidedisolvate AT yaminboharim e23cinnamoylthioureidoaceticaciddimethylsulfoxidedisolvate AT kassimmohammadb e23cinnamoylthioureidoaceticaciddimethylsulfoxidedisolvate |