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Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri
The title compound [systematic name: 5,10-dihydroxy-2,2-dimethyl-12-(2-methylbut-3-en-2-yl)pyrano[3,2-b]xanthen-6(2H)-one], C(23)H(22)O(5), isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methylbut-3-en-2-yl side chain. The tricyclic xanthone r...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201296/ https://www.ncbi.nlm.nih.gov/pubmed/22064829 http://dx.doi.org/10.1107/S1600536811036294 |
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author | Ee, Gwendoline Cheng Lian Mah, Siau Hui Kwong, Huey Chong Teh, Soek Sin Mohamed Tahir, Mohamed Ibrahim Silong, Sidik |
author_facet | Ee, Gwendoline Cheng Lian Mah, Siau Hui Kwong, Huey Chong Teh, Soek Sin Mohamed Tahir, Mohamed Ibrahim Silong, Sidik |
author_sort | Ee, Gwendoline Cheng Lian |
collection | PubMed |
description | The title compound [systematic name: 5,10-dihydroxy-2,2-dimethyl-12-(2-methylbut-3-en-2-yl)pyrano[3,2-b]xanthen-6(2H)-one], C(23)H(22)O(5), isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methylbut-3-en-2-yl side chain. The tricyclic xanthone ring system is almost planar [maximum deviation = 0.093 (2) Å], whereas the pyranoid ring is in a distorted boat conformation. The 2-methylbut-3-en-2-yl side chain is in a synperiplanar conformation. There are two intramolecular O—H⋯O hydrogen bonds. In the crystal, molecules are linked by C—H⋯O interactions, forming a zigzag chain propagating in [010]. |
format | Online Article Text |
id | pubmed-3201296 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32012962011-11-06 Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri Ee, Gwendoline Cheng Lian Mah, Siau Hui Kwong, Huey Chong Teh, Soek Sin Mohamed Tahir, Mohamed Ibrahim Silong, Sidik Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: 5,10-dihydroxy-2,2-dimethyl-12-(2-methylbut-3-en-2-yl)pyrano[3,2-b]xanthen-6(2H)-one], C(23)H(22)O(5), isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methylbut-3-en-2-yl side chain. The tricyclic xanthone ring system is almost planar [maximum deviation = 0.093 (2) Å], whereas the pyranoid ring is in a distorted boat conformation. The 2-methylbut-3-en-2-yl side chain is in a synperiplanar conformation. There are two intramolecular O—H⋯O hydrogen bonds. In the crystal, molecules are linked by C—H⋯O interactions, forming a zigzag chain propagating in [010]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201296/ /pubmed/22064829 http://dx.doi.org/10.1107/S1600536811036294 Text en © Ee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ee, Gwendoline Cheng Lian Mah, Siau Hui Kwong, Huey Chong Teh, Soek Sin Mohamed Tahir, Mohamed Ibrahim Silong, Sidik Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri |
title | Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri
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title_full | Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri
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title_fullStr | Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri
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title_full_unstemmed | Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri
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title_short | Caloxanthone C: a pyranoxanthone from the stem bark of Calophyllum soulattri
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title_sort | caloxanthone c: a pyranoxanthone from the stem bark of calophyllum soulattri |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201296/ https://www.ncbi.nlm.nih.gov/pubmed/22064829 http://dx.doi.org/10.1107/S1600536811036294 |
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