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Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri

The title compound [systematic name: 5,10-di­hy­droxy-2,2-di­methyl-12-(2-methyl­but-3-en-2-yl)­pyrano[3,2-b]xanthen-6(2H)-one], C(23)H(22)O(5), isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methyl­but-3-en-2-yl side chain. The tricyclic xanthone r...

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Autores principales: Ee, Gwendoline Cheng Lian, Mah, Siau Hui, Kwong, Huey Chong, Teh, Soek Sin, Mohamed Tahir, Mohamed Ibrahim, Silong, Sidik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201296/
https://www.ncbi.nlm.nih.gov/pubmed/22064829
http://dx.doi.org/10.1107/S1600536811036294
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author Ee, Gwendoline Cheng Lian
Mah, Siau Hui
Kwong, Huey Chong
Teh, Soek Sin
Mohamed Tahir, Mohamed Ibrahim
Silong, Sidik
author_facet Ee, Gwendoline Cheng Lian
Mah, Siau Hui
Kwong, Huey Chong
Teh, Soek Sin
Mohamed Tahir, Mohamed Ibrahim
Silong, Sidik
author_sort Ee, Gwendoline Cheng Lian
collection PubMed
description The title compound [systematic name: 5,10-di­hy­droxy-2,2-di­methyl-12-(2-methyl­but-3-en-2-yl)­pyrano[3,2-b]xanthen-6(2H)-one], C(23)H(22)O(5), isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methyl­but-3-en-2-yl side chain. The tricyclic xanthone ring system is almost planar [maximum deviation = 0.093 (2) Å], whereas the pyran­oid ring is in a distorted boat conformation. The 2-methyl­but-3-en-2-yl side chain is in a synperiplanar conformation. There are two intra­molecular O—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, forming a zigzag chain propagating in [010].
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spelling pubmed-32012962011-11-06 Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri Ee, Gwendoline Cheng Lian Mah, Siau Hui Kwong, Huey Chong Teh, Soek Sin Mohamed Tahir, Mohamed Ibrahim Silong, Sidik Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: 5,10-di­hy­droxy-2,2-di­methyl-12-(2-methyl­but-3-en-2-yl)­pyrano[3,2-b]xanthen-6(2H)-one], C(23)H(22)O(5), isolated from the stem bark of Calophyllum soulattri, consists of four six-membered rings and a 2-methyl­but-3-en-2-yl side chain. The tricyclic xanthone ring system is almost planar [maximum deviation = 0.093 (2) Å], whereas the pyran­oid ring is in a distorted boat conformation. The 2-methyl­but-3-en-2-yl side chain is in a synperiplanar conformation. There are two intra­molecular O—H⋯O hydrogen bonds. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, forming a zigzag chain propagating in [010]. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201296/ /pubmed/22064829 http://dx.doi.org/10.1107/S1600536811036294 Text en © Ee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ee, Gwendoline Cheng Lian
Mah, Siau Hui
Kwong, Huey Chong
Teh, Soek Sin
Mohamed Tahir, Mohamed Ibrahim
Silong, Sidik
Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri
title Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri
title_full Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri
title_fullStr Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri
title_full_unstemmed Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri
title_short Caloxanthone C: a pyran­oxanthone from the stem bark of Calophyllum soulattri
title_sort caloxanthone c: a pyran­oxanthone from the stem bark of calophyllum soulattri
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201296/
https://www.ncbi.nlm.nih.gov/pubmed/22064829
http://dx.doi.org/10.1107/S1600536811036294
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