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{5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4) O,N,N′,O′}copper(II) monohydrate
The tetradentate dianion in the title complex hydrate, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, provides the Cu(II) atom with a cis-N(2)O(2) donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC(3)N chelate rings being...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201301/ https://www.ncbi.nlm.nih.gov/pubmed/22058715 http://dx.doi.org/10.1107/S160053681103889X |
| _version_ | 1782214843040792576 |
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| author | Ghaemi, Akbar Rayati, Saeed Elahi, Ehsan Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Ghaemi, Akbar Rayati, Saeed Elahi, Ehsan Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Ghaemi, Akbar |
| collection | PubMed |
| description | The tetradentate dianion in the title complex hydrate, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, provides the Cu(II) atom with a cis-N(2)O(2) donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC(3)N chelate rings being 32.14 (8)°. The water molecule forms hydrogen bonds to each of the coordinating O atoms of a given complex molecule. Supramolecular layers in the bc plane are formed in the crystal packing through C—H⋯O and C—H⋯π interactions. |
| format | Online Article Text |
| id | pubmed-3201301 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32013012011-11-06 {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4) O,N,N′,O′}copper(II) monohydrate Ghaemi, Akbar Rayati, Saeed Elahi, Ehsan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tetradentate dianion in the title complex hydrate, [Cu(C(23)H(28)N(2)O(4))]·H(2)O, provides the Cu(II) atom with a cis-N(2)O(2) donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC(3)N chelate rings being 32.14 (8)°. The water molecule forms hydrogen bonds to each of the coordinating O atoms of a given complex molecule. Supramolecular layers in the bc plane are formed in the crystal packing through C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201301/ /pubmed/22058715 http://dx.doi.org/10.1107/S160053681103889X Text en © Ghaemi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ghaemi, Akbar Rayati, Saeed Elahi, Ehsan Ng, Seik Weng Tiekink, Edward R. T. {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4) O,N,N′,O′}copper(II) monohydrate |
| title | {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4)
O,N,N′,O′}copper(II) monohydrate |
| title_full | {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4)
O,N,N′,O′}copper(II) monohydrate |
| title_fullStr | {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4)
O,N,N′,O′}copper(II) monohydrate |
| title_full_unstemmed | {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4)
O,N,N′,O′}copper(II) monohydrate |
| title_short | {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4)
O,N,N′,O′}copper(II) monohydrate |
| title_sort | {5,5′-dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1,3-diyldinitrilo)diethylidyne]diphenolato-κ(4)
o,n,n′,o′}copper(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201301/ https://www.ncbi.nlm.nih.gov/pubmed/22058715 http://dx.doi.org/10.1107/S160053681103889X |
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