(7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane

In the title compound, C(26)H(31)NO(4), a sinomenine derivative, the angle between the two aromatic rings is 53.34 (4)°. The N-containing ring is in a chair conformation, while the other two non-planar rings are in a half-boat conformation. In the crystal, mol­ecules are linked by O—H⋯N inter­action...

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Autores principales: Zheng, Xing-Liang, Jiang, Ning-Fei, Luo, Dan, Gao, Hong-Sheng, Ding, Ai-Shun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201304/
https://www.ncbi.nlm.nih.gov/pubmed/22058779
http://dx.doi.org/10.1107/S1600536811037226
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author Zheng, Xing-Liang
Jiang, Ning-Fei
Luo, Dan
Gao, Hong-Sheng
Ding, Ai-Shun
author_facet Zheng, Xing-Liang
Jiang, Ning-Fei
Luo, Dan
Gao, Hong-Sheng
Ding, Ai-Shun
author_sort Zheng, Xing-Liang
collection PubMed
description In the title compound, C(26)H(31)NO(4), a sinomenine derivative, the angle between the two aromatic rings is 53.34 (4)°. The N-containing ring is in a chair conformation, while the other two non-planar rings are in a half-boat conformation. In the crystal, mol­ecules are linked by O—H⋯N inter­actions into a C(8) chain along [100].
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spelling pubmed-32013042011-11-06 (7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane Zheng, Xing-Liang Jiang, Ning-Fei Luo, Dan Gao, Hong-Sheng Ding, Ai-Shun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(31)NO(4), a sinomenine derivative, the angle between the two aromatic rings is 53.34 (4)°. The N-containing ring is in a chair conformation, while the other two non-planar rings are in a half-boat conformation. In the crystal, mol­ecules are linked by O—H⋯N inter­actions into a C(8) chain along [100]. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201304/ /pubmed/22058779 http://dx.doi.org/10.1107/S1600536811037226 Text en © Zheng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zheng, Xing-Liang
Jiang, Ning-Fei
Luo, Dan
Gao, Hong-Sheng
Ding, Ai-Shun
(7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane
title (7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane
title_full (7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane
title_fullStr (7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane
title_full_unstemmed (7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane
title_short (7R,8S,9S,12S)-1-Benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-N-methyl­morphinane
title_sort (7r,8s,9s,12s)-1-benz­yloxy-13,14-didehydro-12-hy­droxy-2,13-dimeth­oxy-n-methyl­morphinane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201304/
https://www.ncbi.nlm.nih.gov/pubmed/22058779
http://dx.doi.org/10.1107/S1600536811037226
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