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Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)

In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water mol­ecule and a monodentate dicyan­amide group in a distorted octa­hedral geom...

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Detalles Bibliográficos
Autores principales: Cui, Feng-Hua, Zhao, Pei-Zheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201307/
https://www.ncbi.nlm.nih.gov/pubmed/22065101
http://dx.doi.org/10.1107/S1600536811035148
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author Cui, Feng-Hua
Zhao, Pei-Zheng
author_facet Cui, Feng-Hua
Zhao, Pei-Zheng
author_sort Cui, Feng-Hua
collection PubMed
description In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water mol­ecule and a monodentate dicyan­amide group in a distorted octa­hedral geometry. One uncoordinated dmphen mol­ecule is situated on a crystallographic twofold axis and the asymmetric unit is completed by one water mol­ecule. In the crystal, mol­ecules form a one-dimensional framework in the [001] direction through O—H⋯N and O—H⋯O hydrogen bonds. The crystal packing is further stabilized by π–π stacking inter­actions between the dmphen rings of neighboring mol­ecules, with a centroid–centroid separation of 3.5641 (8) Å and a partially overlapped arrangement of parallel dmphen rings with a distance of 3.407 (2) Å.
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spelling pubmed-32013072011-11-06 Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) Cui, Feng-Hua Zhao, Pei-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water mol­ecule and a monodentate dicyan­amide group in a distorted octa­hedral geometry. One uncoordinated dmphen mol­ecule is situated on a crystallographic twofold axis and the asymmetric unit is completed by one water mol­ecule. In the crystal, mol­ecules form a one-dimensional framework in the [001] direction through O—H⋯N and O—H⋯O hydrogen bonds. The crystal packing is further stabilized by π–π stacking inter­actions between the dmphen rings of neighboring mol­ecules, with a centroid–centroid separation of 3.5641 (8) Å and a partially overlapped arrangement of parallel dmphen rings with a distance of 3.407 (2) Å. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201307/ /pubmed/22065101 http://dx.doi.org/10.1107/S1600536811035148 Text en © Cui and Zhao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Feng-Hua
Zhao, Pei-Zheng
Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
title Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
title_full Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
title_fullStr Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
title_full_unstemmed Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
title_short Aqua­(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
title_sort aqua­(dicyanamido-κn (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) n,n′)(nitrato-κ(2) o,o′)cobalt(ii)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201307/
https://www.ncbi.nlm.nih.gov/pubmed/22065101
http://dx.doi.org/10.1107/S1600536811035148
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