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Aqua(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2)
In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water molecule and a monodentate dicyanamide group in a distorted octahedral geom...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201307/ https://www.ncbi.nlm.nih.gov/pubmed/22065101 http://dx.doi.org/10.1107/S1600536811035148 |
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author | Cui, Feng-Hua Zhao, Pei-Zheng |
author_facet | Cui, Feng-Hua Zhao, Pei-Zheng |
author_sort | Cui, Feng-Hua |
collection | PubMed |
description | In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water molecule and a monodentate dicyanamide group in a distorted octahedral geometry. One uncoordinated dmphen molecule is situated on a crystallographic twofold axis and the asymmetric unit is completed by one water molecule. In the crystal, molecules form a one-dimensional framework in the [001] direction through O—H⋯N and O—H⋯O hydrogen bonds. The crystal packing is further stabilized by π–π stacking interactions between the dmphen rings of neighboring molecules, with a centroid–centroid separation of 3.5641 (8) Å and a partially overlapped arrangement of parallel dmphen rings with a distance of 3.407 (2) Å. |
format | Online Article Text |
id | pubmed-3201307 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013072011-11-06 Aqua(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) Cui, Feng-Hua Zhao, Pei-Zheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, 2[Co(C(2)N(3))(NO(3))(C(14)H(12)N(2))(H(2)O)]·C(14)H(12)N(2)·2H(2)O, the Co(II) ion is coordinated by a bidentate 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, a bidentate nitrate anion, a water molecule and a monodentate dicyanamide group in a distorted octahedral geometry. One uncoordinated dmphen molecule is situated on a crystallographic twofold axis and the asymmetric unit is completed by one water molecule. In the crystal, molecules form a one-dimensional framework in the [001] direction through O—H⋯N and O—H⋯O hydrogen bonds. The crystal packing is further stabilized by π–π stacking interactions between the dmphen rings of neighboring molecules, with a centroid–centroid separation of 3.5641 (8) Å and a partially overlapped arrangement of parallel dmphen rings with a distance of 3.407 (2) Å. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201307/ /pubmed/22065101 http://dx.doi.org/10.1107/S1600536811035148 Text en © Cui and Zhao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cui, Feng-Hua Zhao, Pei-Zheng Aqua(dicyanamido-κN (1))(2,9-dimethyl-1,10-phenanthroline-κ(2) N,N′)(nitrato-κ(2) O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
title | Aqua(dicyanamido-κN
(1))(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(nitrato-κ(2)
O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
title_full | Aqua(dicyanamido-κN
(1))(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(nitrato-κ(2)
O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
title_fullStr | Aqua(dicyanamido-κN
(1))(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(nitrato-κ(2)
O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
title_full_unstemmed | Aqua(dicyanamido-κN
(1))(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(nitrato-κ(2)
O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
title_short | Aqua(dicyanamido-κN
(1))(2,9-dimethyl-1,10-phenanthroline-κ(2)
N,N′)(nitrato-κ(2)
O,O′)cobalt(II)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
title_sort | aqua(dicyanamido-κn
(1))(2,9-dimethyl-1,10-phenanthroline-κ(2)
n,n′)(nitrato-κ(2)
o,o′)cobalt(ii)–2,9-dimethyl-1,10-phenanthroline–water (2/1/2) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201307/ https://www.ncbi.nlm.nih.gov/pubmed/22065101 http://dx.doi.org/10.1107/S1600536811035148 |
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