N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine

In the title compound, C(35)H(30)N(4)P(2), the diphenyl­phosphanyl and diphen­yl(2-pyridyl­imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P—C—N angle of 114.09 (16)°. The mol­ecules stack along the b axis and inter­connect through C—H(pyrid­yl)⋯N(pyrid­yl) inter­actio...

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Detalles Bibliográficos
Autores principales: Peng, Xiao, Yuan, Yan, Chen, Xue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201310/
https://www.ncbi.nlm.nih.gov/pubmed/22058786
http://dx.doi.org/10.1107/S1600536811037007
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author Peng, Xiao
Yuan, Yan
Chen, Xue
author_facet Peng, Xiao
Yuan, Yan
Chen, Xue
author_sort Peng, Xiao
collection PubMed
description In the title compound, C(35)H(30)N(4)P(2), the diphenyl­phosphanyl and diphen­yl(2-pyridyl­imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P—C—N angle of 114.09 (16)°. The mol­ecules stack along the b axis and inter­connect through C—H(pyrid­yl)⋯N(pyrid­yl) inter­actions, forming an infinite chain structure. The parallel chains are further inter­connected via C—H(benzene)⋯N(amino) and C—H(benzene)⋯π inter­actions, forming a three-dimensional framework.
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spelling pubmed-32013102011-11-06 N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine Peng, Xiao Yuan, Yan Chen, Xue Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(35)H(30)N(4)P(2), the diphenyl­phosphanyl and diphen­yl(2-pyridyl­imino)-λ(5)-phosphanyl groups are attached to the central methyl C atom with a P—C—N angle of 114.09 (16)°. The mol­ecules stack along the b axis and inter­connect through C—H(pyrid­yl)⋯N(pyrid­yl) inter­actions, forming an infinite chain structure. The parallel chains are further inter­connected via C—H(benzene)⋯N(amino) and C—H(benzene)⋯π inter­actions, forming a three-dimensional framework. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201310/ /pubmed/22058786 http://dx.doi.org/10.1107/S1600536811037007 Text en © Peng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Peng, Xiao
Yuan, Yan
Chen, Xue
N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
title N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
title_full N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
title_fullStr N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
title_full_unstemmed N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
title_short N-Diphenyl­phosphanyl-N-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
title_sort n-diphenyl­phosphanyl-n-{[diphen­yl(2-pyridyl­imino)-λ(5)-phosphan­yl]meth­yl}pyridin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201310/
https://www.ncbi.nlm.nih.gov/pubmed/22058786
http://dx.doi.org/10.1107/S1600536811037007
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AT chenxue ndiphenylphosphanylndiphenyl2pyridyliminol5phosphanylmethylpyridin2amine

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