(Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate

In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by...

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Detalles Bibliográficos
Autores principales: Gangadharan, Rajeswari, Sethusankar, K., Selvakumar, Raman, Bakthadoss, Manickam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201315/
https://www.ncbi.nlm.nih.gov/pubmed/22058801
http://dx.doi.org/10.1107/S1600536811037925
Descripción
Sumario:In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by 0.226 (2) Å. The methyl acrylate group adopts an E conformation. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(24) loops.

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