(Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate

In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by...

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Detalles Bibliográficos
Autores principales: Gangadharan, Rajeswari, Sethusankar, K., Selvakumar, Raman, Bakthadoss, Manickam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201315/
https://www.ncbi.nlm.nih.gov/pubmed/22058801
http://dx.doi.org/10.1107/S1600536811037925
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author Gangadharan, Rajeswari
Sethusankar, K.
Selvakumar, Raman
Bakthadoss, Manickam
author_facet Gangadharan, Rajeswari
Sethusankar, K.
Selvakumar, Raman
Bakthadoss, Manickam
author_sort Gangadharan, Rajeswari
collection PubMed
description In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by 0.226 (2) Å. The methyl acrylate group adopts an E conformation. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(24) loops.
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spelling pubmed-32013152011-11-06 (Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate Gangadharan, Rajeswari Sethusankar, K. Selvakumar, Raman Bakthadoss, Manickam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by 0.226 (2) Å. The methyl acrylate group adopts an E conformation. In the crystal, inversion dimers linked by pairs of C—H⋯O hydrogen bonds generate R (2) (2)(24) loops. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201315/ /pubmed/22058801 http://dx.doi.org/10.1107/S1600536811037925 Text en © Gangadharan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gangadharan, Rajeswari
Sethusankar, K.
Selvakumar, Raman
Bakthadoss, Manickam
(Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
title (Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
title_full (Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
title_fullStr (Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
title_full_unstemmed (Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
title_short (Z)-Methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
title_sort (z)-methyl 3-(2,4-dichloro­phen­yl)-2-[(2-formyl­phen­oxy)meth­yl]acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201315/
https://www.ncbi.nlm.nih.gov/pubmed/22058801
http://dx.doi.org/10.1107/S1600536811037925
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AT selvakumarraman zmethyl324dichlorophenyl22formylphenoxymethylacrylate
AT bakthadossmanickam zmethyl324dichlorophenyl22formylphenoxymethylacrylate

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