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Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2) N (3):N (3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2) O (3):O (5))zinc] dihydrate]
In the title coordination polymer, {[Zn(C(9)H(7)NO(4))(C(10)H(14)N(4))]·2H(2)O}(n), the Zn(II) ion displays a distorted tetrahedral geometry with two imidazole N atoms from two 1,1′-(butane-1,4-diyl)bis(imidazole) (bbi) ligands and two carboxylate O atoms from two 2,6-dimethylpyridine-3,5-dicar...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201321/ https://www.ncbi.nlm.nih.gov/pubmed/22058724 http://dx.doi.org/10.1107/S1600536811039481 |
| _version_ | 1782214847564349440 |
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| author | Yue, Yu-Mei Qian, Lei Zhu, Zheng-Hao Wang, Cheng Gao, Ting |
| author_facet | Yue, Yu-Mei Qian, Lei Zhu, Zheng-Hao Wang, Cheng Gao, Ting |
| author_sort | Yue, Yu-Mei |
| collection | PubMed |
| description | In the title coordination polymer, {[Zn(C(9)H(7)NO(4))(C(10)H(14)N(4))]·2H(2)O}(n), the Zn(II) ion displays a distorted tetrahedral geometry with two imidazole N atoms from two 1,1′-(butane-1,4-diyl)bis(imidazole) (bbi) ligands and two carboxylate O atoms from two 2,6-dimethylpyridine-3,5-dicarboxylate (dpdc) ligands. The bbi and dpdc ligands bridge the Zn(II) ions, forming layers parallel to (011). O—H⋯O and O—H⋯N hydrogen bonds and π–π interactions between the imidazole rings [centroid–centroid distance = 3.807 (5) Å] connect the layers. Two of the three uncoordinated water molecules are disordered, each over two 0.25-occupancy positions. |
| format | Online Article Text |
| id | pubmed-3201321 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32013212011-11-06 Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2) N (3):N (3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2) O (3):O (5))zinc] dihydrate] Yue, Yu-Mei Qian, Lei Zhu, Zheng-Hao Wang, Cheng Gao, Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Zn(C(9)H(7)NO(4))(C(10)H(14)N(4))]·2H(2)O}(n), the Zn(II) ion displays a distorted tetrahedral geometry with two imidazole N atoms from two 1,1′-(butane-1,4-diyl)bis(imidazole) (bbi) ligands and two carboxylate O atoms from two 2,6-dimethylpyridine-3,5-dicarboxylate (dpdc) ligands. The bbi and dpdc ligands bridge the Zn(II) ions, forming layers parallel to (011). O—H⋯O and O—H⋯N hydrogen bonds and π–π interactions between the imidazole rings [centroid–centroid distance = 3.807 (5) Å] connect the layers. Two of the three uncoordinated water molecules are disordered, each over two 0.25-occupancy positions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201321/ /pubmed/22058724 http://dx.doi.org/10.1107/S1600536811039481 Text en © Yue et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yue, Yu-Mei Qian, Lei Zhu, Zheng-Hao Wang, Cheng Gao, Ting Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2) N (3):N (3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2) O (3):O (5))zinc] dihydrate] |
| title | Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2)
N
(3):N
(3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2)
O
(3):O
(5))zinc] dihydrate] |
| title_full | Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2)
N
(3):N
(3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2)
O
(3):O
(5))zinc] dihydrate] |
| title_fullStr | Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2)
N
(3):N
(3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2)
O
(3):O
(5))zinc] dihydrate] |
| title_full_unstemmed | Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2)
N
(3):N
(3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2)
O
(3):O
(5))zinc] dihydrate] |
| title_short | Poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1H-imidazole)-κ(2)
N
(3):N
(3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2)
O
(3):O
(5))zinc] dihydrate] |
| title_sort | poly[[[μ(2)-1,1′-(butane-1,4-diyl)bis(1h-imidazole)-κ(2)
n
(3):n
(3′)](μ(2)-2,6-dimethylpyridine-3,5-dicarboxylato-κ(2)
o
(3):o
(5))zinc] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201321/ https://www.ncbi.nlm.nih.gov/pubmed/22058724 http://dx.doi.org/10.1107/S1600536811039481 |
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