trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate

In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl­phosphine, the Rh—P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh—Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar...

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Detalles Bibliográficos
Autor principal: Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201328/
https://www.ncbi.nlm.nih.gov/pubmed/22065702
http://dx.doi.org/10.1107/S1600536811038505
Descripción
Sumario:In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl­phosphine, the Rh—P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh—Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.

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