trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate

In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl­phosphine, the Rh—P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh—Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar...

Descripción completa

Detalles Bibliográficos
Autor principal: Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201328/
https://www.ncbi.nlm.nih.gov/pubmed/22065702
http://dx.doi.org/10.1107/S1600536811038505
_version_ 1782214849430814720
author Meijboom, Reinout
author_facet Meijboom, Reinout
author_sort Meijboom, Reinout
collection PubMed
description In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl­phosphine, the Rh—P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh—Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement.
format Online
Article
Text
id pubmed-3201328
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32013282011-11-06 trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, trans-[RhCl{P(C(10)H(7))(3)}(2)(CO)]·3C(3)H(6)O, where P(C(10)H(7))(3) is trinaphthyl­phosphine, the Rh—P bond lengths are 2.3360 (10) and 2.3258 (10) Å, while the Rh—Cl bond length is 2.3525 (11) Å. The coordination around the Rh atom shows a slightly distorted square-planar arrangement. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201328/ /pubmed/22065702 http://dx.doi.org/10.1107/S1600536811038505 Text en © Reinout Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meijboom, Reinout
trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate
title trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate
title_full trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate
title_fullStr trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate
title_full_unstemmed trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate
title_short trans-Carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κP]rhodium(I) acetone trisolvate
title_sort trans-carbonyl­chloridobis[tris(naph­thalen-1-yl)­phosphane-κp]rhodium(i) acetone trisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201328/
https://www.ncbi.nlm.nih.gov/pubmed/22065702
http://dx.doi.org/10.1107/S1600536811038505
work_keys_str_mv AT meijboomreinout transcarbonylchloridobistrisnaphthalen1ylphosphanekprhodiumiacetonetrisolvate

Ejemplares similares