Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)

In the title compound, [Fe(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)] or [Fe(POA)(2)(H(2)O)(4)], the Fe(II) atom is located on an inversion center and is ligated by four O atoms of coordinated water mol­ecules in the equatorial plane while two POA ligands acting as monodentate ligands occupy the axial positio...

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Detalles Bibliográficos
Autores principales: Wang, Hai-Rong, Li, Guo-Ting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201331/
https://www.ncbi.nlm.nih.gov/pubmed/22058719
http://dx.doi.org/10.1107/S1600536811038918
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author Wang, Hai-Rong
Li, Guo-Ting
author_facet Wang, Hai-Rong
Li, Guo-Ting
author_sort Wang, Hai-Rong
collection PubMed
description In the title compound, [Fe(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)] or [Fe(POA)(2)(H(2)O)(4)], the Fe(II) atom is located on an inversion center and is ligated by four O atoms of coordinated water mol­ecules in the equatorial plane while two POA ligands acting as monodentate ligands occupy the axial positions through their pyridyl N atoms, completing a slightly distorted octa­hedral coordination geometry. A three-dimensional supra­molecular network is formed by multiple O—H⋯O hydrogen-bonding inter­actions between the coordinated water donors and the uncoordinated carboxyl acceptors.
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spelling pubmed-32013312011-11-06 Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II) Wang, Hai-Rong Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)] or [Fe(POA)(2)(H(2)O)(4)], the Fe(II) atom is located on an inversion center and is ligated by four O atoms of coordinated water mol­ecules in the equatorial plane while two POA ligands acting as monodentate ligands occupy the axial positions through their pyridyl N atoms, completing a slightly distorted octa­hedral coordination geometry. A three-dimensional supra­molecular network is formed by multiple O—H⋯O hydrogen-bonding inter­actions between the coordinated water donors and the uncoordinated carboxyl acceptors. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201331/ /pubmed/22058719 http://dx.doi.org/10.1107/S1600536811038918 Text en © Wang and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Hai-Rong
Li, Guo-Ting
Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)
title Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)
title_full Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)
title_fullStr Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)
title_full_unstemmed Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)
title_short Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(II)
title_sort tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201331/
https://www.ncbi.nlm.nih.gov/pubmed/22058719
http://dx.doi.org/10.1107/S1600536811038918
work_keys_str_mv AT wanghairong tetraaquabis25pyridin4yl134oxadiazol2ylsulfanylacetatoironii
AT liguoting tetraaquabis25pyridin4yl134oxadiazol2ylsulfanylacetatoironii

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