Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide

In the anion of the title salt, C(7)H(16)N(+)·C(21)H(35)N(3)O(3)PS(−), the P and S atoms are both in distorted tetra­hedral environments and the angles at the tertiary N atoms confirm their sp (2) character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group....

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Autores principales: Pourayoubi, Mehrdad, Fadaei, Hassan, Tarahhomi, Atekeh, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201332/
https://www.ncbi.nlm.nih.gov/pubmed/22065725
http://dx.doi.org/10.1107/S160053681103950X
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author Pourayoubi, Mehrdad
Fadaei, Hassan
Tarahhomi, Atekeh
Parvez, Masood
author_facet Pourayoubi, Mehrdad
Fadaei, Hassan
Tarahhomi, Atekeh
Parvez, Masood
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the anion of the title salt, C(7)H(16)N(+)·C(21)H(35)N(3)O(3)PS(−), the P and S atoms are both in distorted tetra­hedral environments and the angles at the tertiary N atoms confirm their sp (2) character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group. In the crystal, N—H⋯O(=S) and N—H⋯O(=P) hydrogen bonds involving two anions and two cations form a centrosymmetric four-component cluster.
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spelling pubmed-32013322011-11-06 Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide Pourayoubi, Mehrdad Fadaei, Hassan Tarahhomi, Atekeh Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the anion of the title salt, C(7)H(16)N(+)·C(21)H(35)N(3)O(3)PS(−), the P and S atoms are both in distorted tetra­hedral environments and the angles at the tertiary N atoms confirm their sp (2) character. The two S=O groups are in syn and gauche conformations with respect to the phosphoryl group. In the crystal, N—H⋯O(=S) and N—H⋯O(=P) hydrogen bonds involving two anions and two cations form a centrosymmetric four-component cluster. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201332/ /pubmed/22065725 http://dx.doi.org/10.1107/S160053681103950X Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Fadaei, Hassan
Tarahhomi, Atekeh
Parvez, Masood
Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
title Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
title_full Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
title_fullStr Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
title_full_unstemmed Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
title_short Cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
title_sort cyclo­hex­yl(meth­yl)ammonium {bis­[cyclo­hex­yl(meth­yl)amino]­phosphor­yl}(4-methyl­phenyl­sulfon­yl)aza­nide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201332/
https://www.ncbi.nlm.nih.gov/pubmed/22065725
http://dx.doi.org/10.1107/S160053681103950X
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AT tarahhomiatekeh cyclohexylmethylammoniumbiscyclohexylmethylaminophosphoryl4methylphenylsulfonylazanide
AT parvezmasood cyclohexylmethylammoniumbiscyclohexylmethylaminophosphoryl4methylphenylsulfonylazanide

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