Cargando…
catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate]
In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxylate O atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, two O atoms from two coordinated water molecul...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201333/ https://www.ncbi.nlm.nih.gov/pubmed/22064371 http://dx.doi.org/10.1107/S1600536811038633 |
Sumario: | In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxylate O atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, two O atoms from two coordinated water molecules and two N atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, displaying a slightly distorted NiN(2)O(4) octahedral geometry. Each 3,5-bis(pyridin-4-ylmethylamino)benzoate anion acts as a μ(2)-bridge, linking different nickel ions into a chain along [010]. In the crystal, adjacent chains are further linked through N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The coordinated water molecules and a disordered water molecule of hydration with 0.50 site occupancy play an important role in the formation of these hydrogen-bonding interactions. |
---|