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catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]

In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxyl­ate O atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, two O atoms from two coordinated water mol­ecul...

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Detalles Bibliográficos
Autores principales: Kuai, Hai-Wei, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201333/
https://www.ncbi.nlm.nih.gov/pubmed/22064371
http://dx.doi.org/10.1107/S1600536811038633
Descripción
Sumario:In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxyl­ate O atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, two O atoms from two coordinated water mol­ecules and two N atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, displaying a slightly distorted NiN(2)O(4) octa­hedral geometry. Each 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anion acts as a μ(2)-bridge, linking different nickel ions into a chain along [010]. In the crystal, adjacent chains are further linked through N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The coordinated water mol­ecules and a disordered water mol­ecule of hydration with 0.50 site occupancy play an important role in the formation of these hydrogen-bonding inter­actions.