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catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]

In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxyl­ate O atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, two O atoms from two coordinated water mol­ecul...

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Detalles Bibliográficos
Autores principales: Kuai, Hai-Wei, Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201333/
https://www.ncbi.nlm.nih.gov/pubmed/22064371
http://dx.doi.org/10.1107/S1600536811038633
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author Kuai, Hai-Wei
Cheng, Xiao-Chun
author_facet Kuai, Hai-Wei
Cheng, Xiao-Chun
author_sort Kuai, Hai-Wei
collection PubMed
description In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxyl­ate O atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, two O atoms from two coordinated water mol­ecules and two N atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, displaying a slightly distorted NiN(2)O(4) octa­hedral geometry. Each 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anion acts as a μ(2)-bridge, linking different nickel ions into a chain along [010]. In the crystal, adjacent chains are further linked through N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The coordinated water mol­ecules and a disordered water mol­ecule of hydration with 0.50 site occupancy play an important role in the formation of these hydrogen-bonding inter­actions.
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spelling pubmed-32013332011-11-06 catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate] Kuai, Hai-Wei Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxyl­ate O atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, two O atoms from two coordinated water mol­ecules and two N atoms from two different 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anions, displaying a slightly distorted NiN(2)O(4) octa­hedral geometry. Each 3,5-bis­(pyridin-4-yl­methyl­amino)­benzoate anion acts as a μ(2)-bridge, linking different nickel ions into a chain along [010]. In the crystal, adjacent chains are further linked through N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The coordinated water mol­ecules and a disordered water mol­ecule of hydration with 0.50 site occupancy play an important role in the formation of these hydrogen-bonding inter­actions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201333/ /pubmed/22064371 http://dx.doi.org/10.1107/S1600536811038633 Text en © Kuai and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kuai, Hai-Wei
Cheng, Xiao-Chun
catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
title catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
title_full catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
title_fullStr catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
title_full_unstemmed catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
title_short catena-Poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
title_sort catena-poly[[diaqua­bis­{μ(2)-3,5-bis­[(pyridin-4-yl)methyl­amino]­benzoato}nickel] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201333/
https://www.ncbi.nlm.nih.gov/pubmed/22064371
http://dx.doi.org/10.1107/S1600536811038633
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