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catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate]
In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxylate O atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, two O atoms from two coordinated water molecul...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201333/ https://www.ncbi.nlm.nih.gov/pubmed/22064371 http://dx.doi.org/10.1107/S1600536811038633 |
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author | Kuai, Hai-Wei Cheng, Xiao-Chun |
author_facet | Kuai, Hai-Wei Cheng, Xiao-Chun |
author_sort | Kuai, Hai-Wei |
collection | PubMed |
description | In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxylate O atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, two O atoms from two coordinated water molecules and two N atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, displaying a slightly distorted NiN(2)O(4) octahedral geometry. Each 3,5-bis(pyridin-4-ylmethylamino)benzoate anion acts as a μ(2)-bridge, linking different nickel ions into a chain along [010]. In the crystal, adjacent chains are further linked through N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The coordinated water molecules and a disordered water molecule of hydration with 0.50 site occupancy play an important role in the formation of these hydrogen-bonding interactions. |
format | Online Article Text |
id | pubmed-3201333 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013332011-11-06 catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] Kuai, Hai-Wei Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Ni(C(19)H(17)N(4)O(2))(2)(H(2)O)(2)]·H(2)O}(n), the Ni(2+) cation is located on an inversion center and coordinated by two carboxylate O atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, two O atoms from two coordinated water molecules and two N atoms from two different 3,5-bis(pyridin-4-ylmethylamino)benzoate anions, displaying a slightly distorted NiN(2)O(4) octahedral geometry. Each 3,5-bis(pyridin-4-ylmethylamino)benzoate anion acts as a μ(2)-bridge, linking different nickel ions into a chain along [010]. In the crystal, adjacent chains are further linked through N—H⋯O, O—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds into a three-dimensional network. The coordinated water molecules and a disordered water molecule of hydration with 0.50 site occupancy play an important role in the formation of these hydrogen-bonding interactions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201333/ /pubmed/22064371 http://dx.doi.org/10.1107/S1600536811038633 Text en © Kuai and Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kuai, Hai-Wei Cheng, Xiao-Chun catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
title |
catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
title_full |
catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
title_fullStr |
catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
title_full_unstemmed |
catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
title_short |
catena-Poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
title_sort | catena-poly[[diaquabis{μ(2)-3,5-bis[(pyridin-4-yl)methylamino]benzoato}nickel] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201333/ https://www.ncbi.nlm.nih.gov/pubmed/22064371 http://dx.doi.org/10.1107/S1600536811038633 |
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