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trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN (3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate)
The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carboxy-5-nitrobenzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octahedral geometry. It bonds to two O atoms of two...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201337/ https://www.ncbi.nlm.nih.gov/pubmed/22058688 http://dx.doi.org/10.1107/S1600536811035446 |
Sumario: | The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carboxy-5-nitrobenzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octahedral geometry. It bonds to two O atoms of two water molecules, and two pairs of N atoms from two 4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole molecules, which behave as bidentate chelating ligands. There are intramolecular N—H⋯N hydrogen bonds in the cation. In the crystal, there are a number of intermolecular N—H⋯O and O—H⋯O hydrogen bonds, as well as intermolecular π–π stacking interactions [centroid–centroid distances = 3.657 (2) and 3.847 (2) Å], that link the molecules into two-dimensional networks lying parallel to the ab plane. The presence of C—H⋯O interactions leads to the formation of a three-dimensional network. |
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