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trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN (3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate)
The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carboxy-5-nitrobenzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octahedral geometry. It bonds to two O atoms of two...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201337/ https://www.ncbi.nlm.nih.gov/pubmed/22058688 http://dx.doi.org/10.1107/S1600536811035446 |
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author | Wang, Xi Shao, Chun-Fu Li, Cheng-Peng |
author_facet | Wang, Xi Shao, Chun-Fu Li, Cheng-Peng |
author_sort | Wang, Xi |
collection | PubMed |
description | The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carboxy-5-nitrobenzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octahedral geometry. It bonds to two O atoms of two water molecules, and two pairs of N atoms from two 4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole molecules, which behave as bidentate chelating ligands. There are intramolecular N—H⋯N hydrogen bonds in the cation. In the crystal, there are a number of intermolecular N—H⋯O and O—H⋯O hydrogen bonds, as well as intermolecular π–π stacking interactions [centroid–centroid distances = 3.657 (2) and 3.847 (2) Å], that link the molecules into two-dimensional networks lying parallel to the ab plane. The presence of C—H⋯O interactions leads to the formation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-3201337 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013372011-11-06 trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN (3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) Wang, Xi Shao, Chun-Fu Li, Cheng-Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carboxy-5-nitrobenzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octahedral geometry. It bonds to two O atoms of two water molecules, and two pairs of N atoms from two 4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole molecules, which behave as bidentate chelating ligands. There are intramolecular N—H⋯N hydrogen bonds in the cation. In the crystal, there are a number of intermolecular N—H⋯O and O—H⋯O hydrogen bonds, as well as intermolecular π–π stacking interactions [centroid–centroid distances = 3.657 (2) and 3.847 (2) Å], that link the molecules into two-dimensional networks lying parallel to the ab plane. The presence of C—H⋯O interactions leads to the formation of a three-dimensional network. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201337/ /pubmed/22058688 http://dx.doi.org/10.1107/S1600536811035446 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Xi Shao, Chun-Fu Li, Cheng-Peng trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN (3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) |
title |
trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN
(3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) |
title_full |
trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN
(3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) |
title_fullStr |
trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN
(3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) |
title_full_unstemmed |
trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN
(3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) |
title_short |
trans-Bis[4-amino-3,5-bis(2-pyridyl)-4H-1,2,4-triazole-κN
(3)]diaquacobalt(II) bis(3-carboxy-5-nitrobenzoate) |
title_sort | trans-bis[4-amino-3,5-bis(2-pyridyl)-4h-1,2,4-triazole-κn
(3)]diaquacobalt(ii) bis(3-carboxy-5-nitrobenzoate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201337/ https://www.ncbi.nlm.nih.gov/pubmed/22058688 http://dx.doi.org/10.1107/S1600536811035446 |
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