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trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)

The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carb­oxy-5-nitro­benzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octa­hedral geometry. It bonds to two O atoms of two...

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Detalles Bibliográficos
Autores principales: Wang, Xi, Shao, Chun-Fu, Li, Cheng-Peng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201337/
https://www.ncbi.nlm.nih.gov/pubmed/22058688
http://dx.doi.org/10.1107/S1600536811035446
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author Wang, Xi
Shao, Chun-Fu
Li, Cheng-Peng
author_facet Wang, Xi
Shao, Chun-Fu
Li, Cheng-Peng
author_sort Wang, Xi
collection PubMed
description The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carb­oxy-5-nitro­benzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octa­hedral geometry. It bonds to two O atoms of two water mol­ecules, and two pairs of N atoms from two 4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole mol­ecules, which behave as bidentate chelating ligands. There are intra­molecular N—H⋯N hydrogen bonds in the cation. In the crystal, there are a number of inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, as well as inter­molecular π–π stacking inter­actions [centroid–centroid distances = 3.657 (2) and 3.847 (2) Å], that link the mol­ecules into two-dimensional networks lying parallel to the ab plane. The presence of C—H⋯O inter­actions leads to the formation of a three-dimensional network.
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spelling pubmed-32013372011-11-06 trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate) Wang, Xi Shao, Chun-Fu Li, Cheng-Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(12)H(10)N(6))(2)(H(2)O)(2)](C(8)H(4)NO(6))(2), is composed of a mononuclear cobalt(II) cation and two 3-carb­oxy-5-nitro­benzoate anions for charge balance. In the cation, the Co(II) atom is six-coordinated in a distorted octa­hedral geometry. It bonds to two O atoms of two water mol­ecules, and two pairs of N atoms from two 4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole mol­ecules, which behave as bidentate chelating ligands. There are intra­molecular N—H⋯N hydrogen bonds in the cation. In the crystal, there are a number of inter­molecular N—H⋯O and O—H⋯O hydrogen bonds, as well as inter­molecular π–π stacking inter­actions [centroid–centroid distances = 3.657 (2) and 3.847 (2) Å], that link the mol­ecules into two-dimensional networks lying parallel to the ab plane. The presence of C—H⋯O inter­actions leads to the formation of a three-dimensional network. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201337/ /pubmed/22058688 http://dx.doi.org/10.1107/S1600536811035446 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Xi
Shao, Chun-Fu
Li, Cheng-Peng
trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)
title trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)
title_full trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)
title_fullStr trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)
title_full_unstemmed trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)
title_short trans-Bis[4-amino-3,5-bis­(2-pyrid­yl)-4H-1,2,4-triazole-κN (3)]diaqua­cobalt(II) bis­(3-carb­oxy-5-nitro­benzoate)
title_sort trans-bis[4-amino-3,5-bis­(2-pyrid­yl)-4h-1,2,4-triazole-κn (3)]diaqua­cobalt(ii) bis­(3-carb­oxy-5-nitro­benzoate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201337/
https://www.ncbi.nlm.nih.gov/pubmed/22058688
http://dx.doi.org/10.1107/S1600536811035446
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