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cis-Aqua­bis­(2,2′-bipyrimidine-κ(2) N (1),N (1′))iodidomanganese(II) iodide monohydrate

The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water mol­ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa­hedral environment defined by four N atoms of the two chelating 2...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201340/
https://www.ncbi.nlm.nih.gov/pubmed/22064764
http://dx.doi.org/10.1107/S160053681103875X
Descripción
Sumario:The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(−) anion and a solvent water mol­ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa­hedral environment defined by four N atoms of the two chelating 2,2′-bipyrimidine (bpym) ligands, one I(−) anion and one O atom of a water ligand. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.092 (7) Å] is 79.9 (1)°. In the crystal, the complex, anion and solvent water mol­ecule are linked by inter­molecular O—H⋯O, O—H⋯I and O—H⋯N hydrogen bonds.