4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide

In the title compound, C(11)H(10)BrN(5)OS, the approximately planar pyrazole ring [maximum deviation = 0.014 (2) Å] forms a dihedral angle of 5.49 (13)° with the benzene ring. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked through inter­mol...

Descripción completa

Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Hemamalini, Madhukar, Shetty, Shobhitha, Kalluraya, BalaKrishna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201347/
https://www.ncbi.nlm.nih.gov/pubmed/22064818
http://dx.doi.org/10.1107/S1600536811034726
_version_ 1782214853948080128
author Fun, Hoong-Kun
Hemamalini, Madhukar
Shetty, Shobhitha
Kalluraya, BalaKrishna
author_facet Fun, Hoong-Kun
Hemamalini, Madhukar
Shetty, Shobhitha
Kalluraya, BalaKrishna
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(11)H(10)BrN(5)OS, the approximately planar pyrazole ring [maximum deviation = 0.014 (2) Å] forms a dihedral angle of 5.49 (13)° with the benzene ring. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked through inter­molecular N—H⋯S and N—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). A short Br⋯Br contact of 3.5114 (6) Å is also observed.
format Online
Article
Text
id pubmed-3201347
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32013472011-11-06 4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide Fun, Hoong-Kun Hemamalini, Madhukar Shetty, Shobhitha Kalluraya, BalaKrishna Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(10)BrN(5)OS, the approximately planar pyrazole ring [maximum deviation = 0.014 (2) Å] forms a dihedral angle of 5.49 (13)° with the benzene ring. An intra­molecular N—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked through inter­molecular N—H⋯S and N—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). A short Br⋯Br contact of 3.5114 (6) Å is also observed. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201347/ /pubmed/22064818 http://dx.doi.org/10.1107/S1600536811034726 Text en © Fun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Hemamalini, Madhukar
Shetty, Shobhitha
Kalluraya, BalaKrishna
4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title 4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_full 4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_fullStr 4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_full_unstemmed 4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_short 4-[2-(4-Bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1H-pyrazole-1-carbothio­amide
title_sort 4-[2-(4-bromo­phen­yl)hydrazinyl­idene]-3-methyl-5-oxo-4,5-dihydro-1h-pyrazole-1-carbothio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201347/
https://www.ncbi.nlm.nih.gov/pubmed/22064818
http://dx.doi.org/10.1107/S1600536811034726
work_keys_str_mv AT funhoongkun 424bromophenylhydrazinylidene3methyl5oxo45dihydro1hpyrazole1carbothioamide
AT hemamalinimadhukar 424bromophenylhydrazinylidene3methyl5oxo45dihydro1hpyrazole1carbothioamide
AT shettyshobhitha 424bromophenylhydrazinylidene3methyl5oxo45dihydro1hpyrazole1carbothioamide
AT kallurayabalakrishna 424bromophenylhydrazinylidene3methyl5oxo45dihydro1hpyrazole1carbothioamide

Ejemplares similares