{5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)

In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201348/
https://www.ncbi.nlm.nih.gov/pubmed/22064844
http://dx.doi.org/10.1107/S1600536811035069
Descripción
Sumario:In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).

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