{5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)

In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201348/
https://www.ncbi.nlm.nih.gov/pubmed/22064844
http://dx.doi.org/10.1107/S1600536811035069
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author Kargar, Hadi
Kia, Reza
author_facet Kargar, Hadi
Kia, Reza
author_sort Kargar, Hadi
collection PubMed
description In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18).
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spelling pubmed-32013482011-11-06 {5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI) Kargar, Hadi Kia, Reza Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(C(27)H(38)N(4)O(2))O(2)], the Mo(VI) atom is coordinated by two oxide O atoms and by two O and two N atoms of the tetra­dentate Schiff base ligand in a distorted octa­hedral geometry. The Mo—N bond trans to a terminal oxide group is significantly longer than the other Mo—N bond, which is attributed to the strong trans effect of the oxide O atom. The dihedral angle formed between the substituted benzene rings is 71.79 (14)°. One of the ethyl groups is disordered over two sets of sites, with a refined site-occupancy ratio of 0.588 (18):0.412 (18). International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201348/ /pubmed/22064844 http://dx.doi.org/10.1107/S1600536811035069 Text en © Kargar and Kia 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
{5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)
title {5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)
title_full {5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)
title_fullStr {5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)
title_full_unstemmed {5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)
title_short {5,5′-Bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(VI)
title_sort {5,5′-bis(diethyl­amino)-2,2′-[(2,2-dimethyl­propane-1,3-di­yl)bis­(nitrilo­methanylyl­idene)]diphenolato}dioxido­molybdenum(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201348/
https://www.ncbi.nlm.nih.gov/pubmed/22064844
http://dx.doi.org/10.1107/S1600536811035069
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AT kiareza 55bisdiethylamino2222dimethylpropane13diylbisnitrilomethanylylidenediphenolatodioxidomolybdenumvi

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