3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde

In the title compound, C(16)H(11)ClN(2)O(2), the pyrazole ring makes dihedral angles of 11.88 (13) and 22.33 (13)° with the 3-chloro-2-hy­droxy­benzene group and phenyl rings, respectively. The phenolic hy­droxy group forms an intra­molecular O—H⋯N hydrogen bond with the imine N atom of the pyrazole...

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Autores principales: Lokhande, Pradeep, Hasanzadeh, Kamal, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201353/
https://www.ncbi.nlm.nih.gov/pubmed/22058800
http://dx.doi.org/10.1107/S1600536811038025
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author Lokhande, Pradeep
Hasanzadeh, Kamal
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Lokhande, Pradeep
Hasanzadeh, Kamal
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Lokhande, Pradeep
collection PubMed
description In the title compound, C(16)H(11)ClN(2)O(2), the pyrazole ring makes dihedral angles of 11.88 (13) and 22.33 (13)° with the 3-chloro-2-hy­droxy­benzene group and phenyl rings, respectively. The phenolic hy­droxy group forms an intra­molecular O—H⋯N hydrogen bond with the imine N atom of the pyrazole unit. The formyl group is virtually coplanar with the pyrazole ring [dihedral angle = 4.5 (19)°] and acts as an acceptor in an intra­molecular C—H⋯O hydrogen bond closing seven-membered ring. In the crystal, adjacent mol­ecules are linked through C—H⋯O hydrogen bonds into infinite chains along the b axis.
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spelling pubmed-32013532011-11-06 3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde Lokhande, Pradeep Hasanzadeh, Kamal Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(11)ClN(2)O(2), the pyrazole ring makes dihedral angles of 11.88 (13) and 22.33 (13)° with the 3-chloro-2-hy­droxy­benzene group and phenyl rings, respectively. The phenolic hy­droxy group forms an intra­molecular O—H⋯N hydrogen bond with the imine N atom of the pyrazole unit. The formyl group is virtually coplanar with the pyrazole ring [dihedral angle = 4.5 (19)°] and acts as an acceptor in an intra­molecular C—H⋯O hydrogen bond closing seven-membered ring. In the crystal, adjacent mol­ecules are linked through C—H⋯O hydrogen bonds into infinite chains along the b axis. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201353/ /pubmed/22058800 http://dx.doi.org/10.1107/S1600536811038025 Text en © Lokhande et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lokhande, Pradeep
Hasanzadeh, Kamal
Khaledi, Hamid
Mohd Ali, Hapipah
3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
title 3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
title_full 3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
title_fullStr 3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
title_full_unstemmed 3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
title_short 3-(3-Chloro-2-hy­droxy­phen­yl)-1-phenyl-1H-pyrazole-4-carbaldehyde
title_sort 3-(3-chloro-2-hy­droxy­phen­yl)-1-phenyl-1h-pyrazole-4-carbaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201353/
https://www.ncbi.nlm.nih.gov/pubmed/22058800
http://dx.doi.org/10.1107/S1600536811038025
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AT hasanzadehkamal 33chloro2hydroxyphenyl1phenyl1hpyrazole4carbaldehyde
AT khaledihamid 33chloro2hydroxyphenyl1phenyl1hpyrazole4carbaldehyde
AT mohdalihapipah 33chloro2hydroxyphenyl1phenyl1hpyrazole4carbaldehyde

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