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Poly[[diaquabis(2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(5) O (1),O (1′):O (3),O (3′):O (3′))(μ(3)-5-hydroxyisophthalato-κ(4) O (1),O (1′):O (3):O (3′))(μ(2)-5-hydroxyisophthalato-κ(3) O (1),O (1′):O (3))didysprosium(III)] dihydrate]
The polymeric title compound, {[Dy(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), contains two independent Dy(III) ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One Dy(III) ion is coordinated by five 5-hydroxyisophthalate (hip) ligands...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201354/ https://www.ncbi.nlm.nih.gov/pubmed/22058725 http://dx.doi.org/10.1107/S1600536811039080 |
Sumario: | The polymeric title compound, {[Dy(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), contains two independent Dy(III) ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One Dy(III) ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The Dy(III) ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H⋯O hydrogen bonds are present in the crystal structure. |
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