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Poly[[diaquabis(2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(5) O (1),O (1′):O (3),O (3′):O (3′))(μ(3)-5-hydroxyisophthalato-κ(4) O (1),O (1′):O (3):O (3′))(μ(2)-5-hydroxyisophthalato-κ(3) O (1),O (1′):O (3))didysprosium(III)] dihydrate]
The polymeric title compound, {[Dy(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), contains two independent Dy(III) ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One Dy(III) ion is coordinated by five 5-hydroxyisophthalate (hip) ligands...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201354/ https://www.ncbi.nlm.nih.gov/pubmed/22058725 http://dx.doi.org/10.1107/S1600536811039080 |
| _version_ | 1782214855571275776 |
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| author | Zhang, Yan-Lin |
| author_facet | Zhang, Yan-Lin |
| author_sort | Zhang, Yan-Lin |
| collection | PubMed |
| description | The polymeric title compound, {[Dy(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), contains two independent Dy(III) ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One Dy(III) ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The Dy(III) ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H⋯O hydrogen bonds are present in the crystal structure. |
| format | Online Article Text |
| id | pubmed-3201354 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32013542011-11-06 Poly[[diaquabis(2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(5) O (1),O (1′):O (3),O (3′):O (3′))(μ(3)-5-hydroxyisophthalato-κ(4) O (1),O (1′):O (3):O (3′))(μ(2)-5-hydroxyisophthalato-κ(3) O (1),O (1′):O (3))didysprosium(III)] dihydrate] Zhang, Yan-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, {[Dy(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), contains two independent Dy(III) ions, both of which are nine-coordinated in a distorted tricapped trigonal–prismatic geometry. One Dy(III) ion is coordinated by five 5-hydroxyisophthalate (hip) ligands and one 2,2′-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water molecules. The Dy(III) ions are bridged by the carboxylate groups of the hip ligands, forming a three-dimensional framework. O—H⋯O hydrogen bonds are present in the crystal structure. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201354/ /pubmed/22058725 http://dx.doi.org/10.1107/S1600536811039080 Text en © Yan-Lin Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhang, Yan-Lin Poly[[diaquabis(2,2′-bipyridine-κ(2) N,N′)(μ(3)-5-hydroxyisophthalato-κ(5) O (1),O (1′):O (3),O (3′):O (3′))(μ(3)-5-hydroxyisophthalato-κ(4) O (1),O (1′):O (3):O (3′))(μ(2)-5-hydroxyisophthalato-κ(3) O (1),O (1′):O (3))didysprosium(III)] dihydrate] |
| title | Poly[[diaquabis(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(5)
O
(1),O
(1′):O
(3),O
(3′):O
(3′))(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1),O
(1′):O
(3):O
(3′))(μ(2)-5-hydroxyisophthalato-κ(3)
O
(1),O
(1′):O
(3))didysprosium(III)] dihydrate] |
| title_full | Poly[[diaquabis(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(5)
O
(1),O
(1′):O
(3),O
(3′):O
(3′))(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1),O
(1′):O
(3):O
(3′))(μ(2)-5-hydroxyisophthalato-κ(3)
O
(1),O
(1′):O
(3))didysprosium(III)] dihydrate] |
| title_fullStr | Poly[[diaquabis(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(5)
O
(1),O
(1′):O
(3),O
(3′):O
(3′))(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1),O
(1′):O
(3):O
(3′))(μ(2)-5-hydroxyisophthalato-κ(3)
O
(1),O
(1′):O
(3))didysprosium(III)] dihydrate] |
| title_full_unstemmed | Poly[[diaquabis(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(5)
O
(1),O
(1′):O
(3),O
(3′):O
(3′))(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1),O
(1′):O
(3):O
(3′))(μ(2)-5-hydroxyisophthalato-κ(3)
O
(1),O
(1′):O
(3))didysprosium(III)] dihydrate] |
| title_short | Poly[[diaquabis(2,2′-bipyridine-κ(2)
N,N′)(μ(3)-5-hydroxyisophthalato-κ(5)
O
(1),O
(1′):O
(3),O
(3′):O
(3′))(μ(3)-5-hydroxyisophthalato-κ(4)
O
(1),O
(1′):O
(3):O
(3′))(μ(2)-5-hydroxyisophthalato-κ(3)
O
(1),O
(1′):O
(3))didysprosium(III)] dihydrate] |
| title_sort | poly[[diaquabis(2,2′-bipyridine-κ(2)
n,n′)(μ(3)-5-hydroxyisophthalato-κ(5)
o
(1),o
(1′):o
(3),o
(3′):o
(3′))(μ(3)-5-hydroxyisophthalato-κ(4)
o
(1),o
(1′):o
(3):o
(3′))(μ(2)-5-hydroxyisophthalato-κ(3)
o
(1),o
(1′):o
(3))didysprosium(iii)] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201354/ https://www.ncbi.nlm.nih.gov/pubmed/22058725 http://dx.doi.org/10.1107/S1600536811039080 |
| work_keys_str_mv | AT zhangyanlin polydiaquabis22bipyridinek2nnm35hydroxyisophthalatok5o1o1o3o3o3m35hydroxyisophthalatok4o1o1o3o3m25hydroxyisophthalatok3o1o1o3didysprosiumiiidihydrate |