Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)

The title compound, Th(V(2)O(7))(H(2)O)(2), was synthesized by a hydro­thermal reaction. The crystal structure consists of ThO(7)(OH(2))(2) tricapped trigonal prisms that share edges, forming [ThO(5)(OH(2))(2)](n) chains along [010]. The edge-sharing ThO(7)(OH(2))(2) polyhedra share one edge and fiv...

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Autores principales: Yagoubi, Said, El Ammari, Lahcen, Assani, Abderrazzak, Saadi, Mohamed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201356/
https://www.ncbi.nlm.nih.gov/pubmed/22058682
http://dx.doi.org/10.1107/S1600536811039584
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author Yagoubi, Said
El Ammari, Lahcen
Assani, Abderrazzak
Saadi, Mohamed
author_facet Yagoubi, Said
El Ammari, Lahcen
Assani, Abderrazzak
Saadi, Mohamed
author_sort Yagoubi, Said
collection PubMed
description The title compound, Th(V(2)O(7))(H(2)O)(2), was synthesized by a hydro­thermal reaction. The crystal structure consists of ThO(7)(OH(2))(2) tricapped trigonal prisms that share edges, forming [ThO(5)(OH(2))(2)](n) chains along [010]. The edge-sharing ThO(7)(OH(2))(2) polyhedra share one edge and five vertices with the V(2)O(7) divanadate anions having a nearly ecliptic conformation parallel to [001]. This results in an open framework with the water mol­ecules located in channels. O—H⋯O hydrogen bonding between water molecules and framework O atoms is observed. Bond-valence-sum calculations are in good agreement with the chemical formula of the title compound.
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spelling pubmed-32013562011-11-06 Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2) Yagoubi, Said El Ammari, Lahcen Assani, Abderrazzak Saadi, Mohamed Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Th(V(2)O(7))(H(2)O)(2), was synthesized by a hydro­thermal reaction. The crystal structure consists of ThO(7)(OH(2))(2) tricapped trigonal prisms that share edges, forming [ThO(5)(OH(2))(2)](n) chains along [010]. The edge-sharing ThO(7)(OH(2))(2) polyhedra share one edge and five vertices with the V(2)O(7) divanadate anions having a nearly ecliptic conformation parallel to [001]. This results in an open framework with the water mol­ecules located in channels. O—H⋯O hydrogen bonding between water molecules and framework O atoms is observed. Bond-valence-sum calculations are in good agreement with the chemical formula of the title compound. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201356/ /pubmed/22058682 http://dx.doi.org/10.1107/S1600536811039584 Text en © Yagoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Yagoubi, Said
El Ammari, Lahcen
Assani, Abderrazzak
Saadi, Mohamed
Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)
title Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)
title_full Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)
title_fullStr Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)
title_full_unstemmed Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)
title_short Thorium divanadate dihydrate, Th(V(2)O(7))(H(2)O)(2)
title_sort thorium divanadate dihydrate, th(v(2)o(7))(h(2)o)(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201356/
https://www.ncbi.nlm.nih.gov/pubmed/22058682
http://dx.doi.org/10.1107/S1600536811039584
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