N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide

In the title compound, C(11)H(9)ClN(4)OS(2), the thia­diazole and chloro­phenyl rings are oriented at an angle of 43.1 (1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers...

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Detalles Bibliográficos
Autores principales: Mohan, S., Ananthan, S., Ramesh, P., Saravanan, D., Ponnuswamy, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201361/
https://www.ncbi.nlm.nih.gov/pubmed/22058758
http://dx.doi.org/10.1107/S1600536811035549
Descripción
Sumario:In the title compound, C(11)H(9)ClN(4)OS(2), the thia­diazole and chloro­phenyl rings are oriented at an angle of 43.1 (1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Weak C—H⋯π inter­actions also occur.

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