N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide

In the title compound, C(11)H(9)ClN(4)OS(2), the thia­diazole and chloro­phenyl rings are oriented at an angle of 43.1 (1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers...

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Detalles Bibliográficos
Autores principales: Mohan, S., Ananthan, S., Ramesh, P., Saravanan, D., Ponnuswamy, M. N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201361/
https://www.ncbi.nlm.nih.gov/pubmed/22058758
http://dx.doi.org/10.1107/S1600536811035549
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author Mohan, S.
Ananthan, S.
Ramesh, P.
Saravanan, D.
Ponnuswamy, M. N.
author_facet Mohan, S.
Ananthan, S.
Ramesh, P.
Saravanan, D.
Ponnuswamy, M. N.
author_sort Mohan, S.
collection PubMed
description In the title compound, C(11)H(9)ClN(4)OS(2), the thia­diazole and chloro­phenyl rings are oriented at an angle of 43.1 (1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Weak C—H⋯π inter­actions also occur.
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spelling pubmed-32013612011-11-06 N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide Mohan, S. Ananthan, S. Ramesh, P. Saravanan, D. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(9)ClN(4)OS(2), the thia­diazole and chloro­phenyl rings are oriented at an angle of 43.1 (1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(8) loops. Weak C—H⋯π inter­actions also occur. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201361/ /pubmed/22058758 http://dx.doi.org/10.1107/S1600536811035549 Text en © Mohan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohan, S.
Ananthan, S.
Ramesh, P.
Saravanan, D.
Ponnuswamy, M. N.
N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
title N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
title_full N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
title_fullStr N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
title_full_unstemmed N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
title_short N′-[(E)-2-Chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
title_sort n′-[(e)-2-chloro­benzyl­idene]-2-[(1,3,4-thia­diazol-2-yl)sulfan­yl]acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201361/
https://www.ncbi.nlm.nih.gov/pubmed/22058758
http://dx.doi.org/10.1107/S1600536811035549
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