catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]

The title compound, {[Ag(C(19)H(16)N(8))](CF(3)SO(3))}(n), is a coordin­ation polymer with cationic chain motif. The Ag(+) cation is coordinated by two unsubstituted imidazolyl N atoms of two independent 2-paBIM ligands [2-paBIM is bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane]. The shortes...

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Detalles Bibliográficos
Autores principales: Wang, Tao, Xu, Ji-Jun, Jin, Chuan-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201363/
https://www.ncbi.nlm.nih.gov/pubmed/22065630
http://dx.doi.org/10.1107/S1600536811035951
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author Wang, Tao
Xu, Ji-Jun
Jin, Chuan-Ming
author_facet Wang, Tao
Xu, Ji-Jun
Jin, Chuan-Ming
author_sort Wang, Tao
collection PubMed
description The title compound, {[Ag(C(19)H(16)N(8))](CF(3)SO(3))}(n), is a coordin­ation polymer with cationic chain motif. The Ag(+) cation is coordinated by two unsubstituted imidazolyl N atoms of two independent 2-paBIM ligands [2-paBIM is bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane]. The shortest Ag⋯Ag separation in a cationic chain is 8.841 (2) Å and the dihedral angle between two 2-phenyl­diazenyl-imidazole planes in the same ligand is 74.7 (3)°. Weak C—H⋯O interactions are seen in the crystal.
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spelling pubmed-32013632011-11-06 catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate] Wang, Tao Xu, Ji-Jun Jin, Chuan-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[Ag(C(19)H(16)N(8))](CF(3)SO(3))}(n), is a coordin­ation polymer with cationic chain motif. The Ag(+) cation is coordinated by two unsubstituted imidazolyl N atoms of two independent 2-paBIM ligands [2-paBIM is bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane]. The shortest Ag⋯Ag separation in a cationic chain is 8.841 (2) Å and the dihedral angle between two 2-phenyl­diazenyl-imidazole planes in the same ligand is 74.7 (3)°. Weak C—H⋯O interactions are seen in the crystal. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201363/ /pubmed/22065630 http://dx.doi.org/10.1107/S1600536811035951 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Tao
Xu, Ji-Jun
Jin, Chuan-Ming
catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
title catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
title_full catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
title_fullStr catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
title_full_unstemmed catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
title_short catena-Poly[[silver(I)-μ-bis­{2-[(E)-phenyl­diazen­yl]-1H-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
title_sort catena-poly[[silver(i)-μ-bis­{2-[(e)-phenyl­diazen­yl]-1h-imidazol-1-yl}methane] trifluoro­methane­sulfonate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201363/
https://www.ncbi.nlm.nih.gov/pubmed/22065630
http://dx.doi.org/10.1107/S1600536811035951
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AT xujijun catenapolysilverimbis2ephenyldiazenyl1himidazol1ylmethanetrifluoromethanesulfonate
AT jinchuanming catenapolysilverimbis2ephenyldiazenyl1himidazol1ylmethanetrifluoromethanesulfonate

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