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2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate
In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (−), centrosymmetrically related cations undergo base pairing via a pair of N—H⋯N hydrogen bonds, forming an R (2) (2)(8) ring motif. The cations and anions interact via N—H⋯F hydrogen bonds, generating supramolecular layers parall...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201368/ https://www.ncbi.nlm.nih.gov/pubmed/22058813 http://dx.doi.org/10.1107/S1600536811038797 |
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author | Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas |
author_facet | Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas |
author_sort | Gomathi, Sundaramoorthy |
collection | PubMed |
description | In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (−), centrosymmetrically related cations undergo base pairing via a pair of N—H⋯N hydrogen bonds, forming an R (2) (2)(8) ring motif. The cations and anions interact via N—H⋯F hydrogen bonds, generating supramolecular layers parallel to ([Image: see text]20), which are in turn linked into a three-dimensional network, forming rings of R (6) (6)(24) graph-set motif. The crystal structure is further stabilized by π–π stacking interactions [centroid–centroid distance = 3.3361 (12) Å]. |
format | Online Article Text |
id | pubmed-3201368 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013682011-11-06 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (−), centrosymmetrically related cations undergo base pairing via a pair of N—H⋯N hydrogen bonds, forming an R (2) (2)(8) ring motif. The cations and anions interact via N—H⋯F hydrogen bonds, generating supramolecular layers parallel to ([Image: see text]20), which are in turn linked into a three-dimensional network, forming rings of R (6) (6)(24) graph-set motif. The crystal structure is further stabilized by π–π stacking interactions [centroid–centroid distance = 3.3361 (12) Å]. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201368/ /pubmed/22058813 http://dx.doi.org/10.1107/S1600536811038797 Text en © Gomathi and Muthiah 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
title | 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
title_full | 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
title_fullStr | 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
title_full_unstemmed | 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
title_short | 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
title_sort | 2,4-diamino-6-methyl-1,3,5-triazin-1-ium tetrafluoroborate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201368/ https://www.ncbi.nlm.nih.gov/pubmed/22058813 http://dx.doi.org/10.1107/S1600536811038797 |
work_keys_str_mv | AT gomathisundaramoorthy 24diamino6methyl135triazin1iumtetrafluoroborate AT muthiahpackianathanthomas 24diamino6methyl135triazin1iumtetrafluoroborate |