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2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate

In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (−), centrosymmetrically related cations undergo base pairing via a pair of N—H⋯N hydrogen bonds, forming an R (2) (2)(8) ring motif. The cations and anions inter­act via N—H⋯F hydrogen bonds, generating supra­molecular layers parall...

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Detalles Bibliográficos
Autores principales: Gomathi, Sundaramoorthy, Muthiah, Packianathan Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201368/
https://www.ncbi.nlm.nih.gov/pubmed/22058813
http://dx.doi.org/10.1107/S1600536811038797
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author Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
author_facet Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
author_sort Gomathi, Sundaramoorthy
collection PubMed
description In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (−), centrosymmetrically related cations undergo base pairing via a pair of N—H⋯N hydrogen bonds, forming an R (2) (2)(8) ring motif. The cations and anions inter­act via N—H⋯F hydrogen bonds, generating supra­molecular layers parallel to ([Image: see text]20), which are in turn linked into a three-dimensional network, forming rings of R (6) (6)(24) graph-set motif. The crystal structure is further stabilized by π–π stacking inter­actions [centroid–centroid distance = 3.3361 (12) Å].
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spelling pubmed-32013682011-11-06 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title salt, C(4)H(8)N(5) (+)·BF(4) (−), centrosymmetrically related cations undergo base pairing via a pair of N—H⋯N hydrogen bonds, forming an R (2) (2)(8) ring motif. The cations and anions inter­act via N—H⋯F hydrogen bonds, generating supra­molecular layers parallel to ([Image: see text]20), which are in turn linked into a three-dimensional network, forming rings of R (6) (6)(24) graph-set motif. The crystal structure is further stabilized by π–π stacking inter­actions [centroid–centroid distance = 3.3361 (12) Å]. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201368/ /pubmed/22058813 http://dx.doi.org/10.1107/S1600536811038797 Text en © Gomathi and Muthiah 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
title 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
title_full 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
title_fullStr 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
title_full_unstemmed 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
title_short 2,4-Diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
title_sort 2,4-diamino-6-methyl-1,3,5-triazin-1-ium tetra­fluoro­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201368/
https://www.ncbi.nlm.nih.gov/pubmed/22058813
http://dx.doi.org/10.1107/S1600536811038797
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