Hydrogen-bond inter­actions in morpholinium bromide

In the title compound, C(4)H(10)NO(+)·Br(−), which was synthesized by dehydration of diethano­lamine with HBr, morpholinium and bromide ions are linked into chains by N—H⋯Br hydrogen bonds describing a C (2) (1)(4) graph-set motif. Weaker bifurcated N—H⋯Br inter­actions join centrosymmetrically rela...

Descripción completa

Detalles Bibliográficos
Autores principales: Padayachy, Kamentheren, Mgcima, Zolani, Fernandes, Manuel A., Marques, Helder M., de Sousa, Alvaro S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201370/
https://www.ncbi.nlm.nih.gov/pubmed/22058749
http://dx.doi.org/10.1107/S1600536811035598
Descripción
Sumario:In the title compound, C(4)H(10)NO(+)·Br(−), which was synthesized by dehydration of diethano­lamine with HBr, morpholinium and bromide ions are linked into chains by N—H⋯Br hydrogen bonds describing a C (2) (1)(4) graph-set motif. Weaker bifurcated N—H⋯Br inter­actions join centrosymmetrically related chains through alternating binary graph-set R (4) (2)(8) and R (2) (2)(4) motifs, to form ladders along [100]. In addition, C—H⋯O inter­actions between centrosymmetric morpholinium cations link ladders, via [Image: see text](8) motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C—H⋯O inter­actions, related across a glide plane, to form a three-dimensional network.

Ejemplares similares