Hydrogen-bond inter­actions in morpholinium bromide

In the title compound, C(4)H(10)NO(+)·Br(−), which was synthesized by dehydration of diethano­lamine with HBr, morpholinium and bromide ions are linked into chains by N—H⋯Br hydrogen bonds describing a C (2) (1)(4) graph-set motif. Weaker bifurcated N—H⋯Br inter­actions join centrosymmetrically rela...

Descripción completa

Detalles Bibliográficos
Autores principales: Padayachy, Kamentheren, Mgcima, Zolani, Fernandes, Manuel A., Marques, Helder M., de Sousa, Alvaro S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201370/
https://www.ncbi.nlm.nih.gov/pubmed/22058749
http://dx.doi.org/10.1107/S1600536811035598
_version_ 1782214859219271680
author Padayachy, Kamentheren
Mgcima, Zolani
Fernandes, Manuel A.
Marques, Helder M.
de Sousa, Alvaro S.
author_facet Padayachy, Kamentheren
Mgcima, Zolani
Fernandes, Manuel A.
Marques, Helder M.
de Sousa, Alvaro S.
author_sort Padayachy, Kamentheren
collection PubMed
description In the title compound, C(4)H(10)NO(+)·Br(−), which was synthesized by dehydration of diethano­lamine with HBr, morpholinium and bromide ions are linked into chains by N—H⋯Br hydrogen bonds describing a C (2) (1)(4) graph-set motif. Weaker bifurcated N—H⋯Br inter­actions join centrosymmetrically related chains through alternating binary graph-set R (4) (2)(8) and R (2) (2)(4) motifs, to form ladders along [100]. In addition, C—H⋯O inter­actions between centrosymmetric morpholinium cations link ladders, via [Image: see text](8) motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C—H⋯O inter­actions, related across a glide plane, to form a three-dimensional network.
format Online
Article
Text
id pubmed-3201370
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32013702011-11-06 Hydrogen-bond inter­actions in morpholinium bromide Padayachy, Kamentheren Mgcima, Zolani Fernandes, Manuel A. Marques, Helder M. de Sousa, Alvaro S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(4)H(10)NO(+)·Br(−), which was synthesized by dehydration of diethano­lamine with HBr, morpholinium and bromide ions are linked into chains by N—H⋯Br hydrogen bonds describing a C (2) (1)(4) graph-set motif. Weaker bifurcated N—H⋯Br inter­actions join centrosymmetrically related chains through alternating binary graph-set R (4) (2)(8) and R (2) (2)(4) motifs, to form ladders along [100]. In addition, C—H⋯O inter­actions between centrosymmetric morpholinium cations link ladders, via [Image: see text](8) motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C—H⋯O inter­actions, related across a glide plane, to form a three-dimensional network. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201370/ /pubmed/22058749 http://dx.doi.org/10.1107/S1600536811035598 Text en © Padayachy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Padayachy, Kamentheren
Mgcima, Zolani
Fernandes, Manuel A.
Marques, Helder M.
de Sousa, Alvaro S.
Hydrogen-bond inter­actions in morpholinium bromide
title Hydrogen-bond inter­actions in morpholinium bromide
title_full Hydrogen-bond inter­actions in morpholinium bromide
title_fullStr Hydrogen-bond inter­actions in morpholinium bromide
title_full_unstemmed Hydrogen-bond inter­actions in morpholinium bromide
title_short Hydrogen-bond inter­actions in morpholinium bromide
title_sort hydrogen-bond inter­actions in morpholinium bromide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201370/
https://www.ncbi.nlm.nih.gov/pubmed/22058749
http://dx.doi.org/10.1107/S1600536811035598
work_keys_str_mv AT padayachykamentheren hydrogenbondinteractionsinmorpholiniumbromide
AT mgcimazolani hydrogenbondinteractionsinmorpholiniumbromide
AT fernandesmanuela hydrogenbondinteractionsinmorpholiniumbromide
AT marqueshelderm hydrogenbondinteractionsinmorpholiniumbromide
AT desousaalvaros hydrogenbondinteractionsinmorpholiniumbromide

Ejemplares similares