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Diaquabis(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)cobalt(II) dihydrate
In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octahedral, with two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands in the equatorial plane. The two remaining coordination sites are occupied by...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201376/ https://www.ncbi.nlm.nih.gov/pubmed/22058711 http://dx.doi.org/10.1107/S1600536811038591 |
Sumario: | In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octahedral, with two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water molecules. In addition, there are two uncoordinated water molecules in the asymmetric unit. The crystal structure is stabilized by a network of O—H⋯O and O—H⋯N hydrogen-bonding interactions, forming a three-dimensional structure. |
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