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Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate

In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa­hedral, with two N atoms and two O atoms from two 5-methyl­pyrazine-2-carboxyl­ate ligands in the equatorial plane. The two remaining coordination sites are occupied by...

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Detalles Bibliográficos
Autores principales: Shi, Qi-Ying, Zhang, Guo-Chun, Zhou, Chun-Sheng, Yang, Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201376/
https://www.ncbi.nlm.nih.gov/pubmed/22058711
http://dx.doi.org/10.1107/S1600536811038591
Descripción
Sumario:In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa­hedral, with two N atoms and two O atoms from two 5-methyl­pyrazine-2-carboxyl­ate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water mol­ecules. In addition, there are two uncoordinated water mol­ecules in the asymmetric unit. The crystal structure is stabilized by a network of O—H⋯O and O—H⋯N hydrogen-bonding inter­actions, forming a three-dimensional structure.