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Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate

In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa­hedral, with two N atoms and two O atoms from two 5-methyl­pyrazine-2-carboxyl­ate ligands in the equatorial plane. The two remaining coordination sites are occupied by...

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Detalles Bibliográficos
Autores principales: Shi, Qi-Ying, Zhang, Guo-Chun, Zhou, Chun-Sheng, Yang, Qi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201376/
https://www.ncbi.nlm.nih.gov/pubmed/22058711
http://dx.doi.org/10.1107/S1600536811038591
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author Shi, Qi-Ying
Zhang, Guo-Chun
Zhou, Chun-Sheng
Yang, Qi
author_facet Shi, Qi-Ying
Zhang, Guo-Chun
Zhou, Chun-Sheng
Yang, Qi
author_sort Shi, Qi-Ying
collection PubMed
description In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa­hedral, with two N atoms and two O atoms from two 5-methyl­pyrazine-2-carboxyl­ate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water mol­ecules. In addition, there are two uncoordinated water mol­ecules in the asymmetric unit. The crystal structure is stabilized by a network of O—H⋯O and O—H⋯N hydrogen-bonding inter­actions, forming a three-dimensional structure.
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spelling pubmed-32013762011-11-06 Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate Shi, Qi-Ying Zhang, Guo-Chun Zhou, Chun-Sheng Yang, Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa­hedral, with two N atoms and two O atoms from two 5-methyl­pyrazine-2-carboxyl­ate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water mol­ecules. In addition, there are two uncoordinated water mol­ecules in the asymmetric unit. The crystal structure is stabilized by a network of O—H⋯O and O—H⋯N hydrogen-bonding inter­actions, forming a three-dimensional structure. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201376/ /pubmed/22058711 http://dx.doi.org/10.1107/S1600536811038591 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Qi-Ying
Zhang, Guo-Chun
Zhou, Chun-Sheng
Yang, Qi
Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate
title Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate
title_full Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate
title_fullStr Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate
title_full_unstemmed Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate
title_short Diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) N (1),O)cobalt(II) dihydrate
title_sort diaqua­bis­(5-methyl­pyrazine-2-carboxyl­ato-κ(2) n (1),o)cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201376/
https://www.ncbi.nlm.nih.gov/pubmed/22058711
http://dx.doi.org/10.1107/S1600536811038591
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