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Diaquabis(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)cobalt(II) dihydrate
In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octahedral, with two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands in the equatorial plane. The two remaining coordination sites are occupied by...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201376/ https://www.ncbi.nlm.nih.gov/pubmed/22058711 http://dx.doi.org/10.1107/S1600536811038591 |
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author | Shi, Qi-Ying Zhang, Guo-Chun Zhou, Chun-Sheng Yang, Qi |
author_facet | Shi, Qi-Ying Zhang, Guo-Chun Zhou, Chun-Sheng Yang, Qi |
author_sort | Shi, Qi-Ying |
collection | PubMed |
description | In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octahedral, with two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water molecules. In addition, there are two uncoordinated water molecules in the asymmetric unit. The crystal structure is stabilized by a network of O—H⋯O and O—H⋯N hydrogen-bonding interactions, forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3201376 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013762011-11-06 Diaquabis(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)cobalt(II) dihydrate Shi, Qi-Ying Zhang, Guo-Chun Zhou, Chun-Sheng Yang, Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octahedral, with two N atoms and two O atoms from two 5-methylpyrazine-2-carboxylate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water molecules. In addition, there are two uncoordinated water molecules in the asymmetric unit. The crystal structure is stabilized by a network of O—H⋯O and O—H⋯N hydrogen-bonding interactions, forming a three-dimensional structure. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201376/ /pubmed/22058711 http://dx.doi.org/10.1107/S1600536811038591 Text en © Shi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi, Qi-Ying Zhang, Guo-Chun Zhou, Chun-Sheng Yang, Qi Diaquabis(5-methylpyrazine-2-carboxylato-κ(2) N (1),O)cobalt(II) dihydrate |
title | Diaquabis(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)cobalt(II) dihydrate |
title_full | Diaquabis(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)cobalt(II) dihydrate |
title_fullStr | Diaquabis(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)cobalt(II) dihydrate |
title_full_unstemmed | Diaquabis(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)cobalt(II) dihydrate |
title_short | Diaquabis(5-methylpyrazine-2-carboxylato-κ(2)
N
(1),O)cobalt(II) dihydrate |
title_sort | diaquabis(5-methylpyrazine-2-carboxylato-κ(2)
n
(1),o)cobalt(ii) dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201376/ https://www.ncbi.nlm.nih.gov/pubmed/22058711 http://dx.doi.org/10.1107/S1600536811038591 |
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