Cargando…
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide
In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetrahedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201378/ https://www.ncbi.nlm.nih.gov/pubmed/22058773 http://dx.doi.org/10.1107/S1600536811036944 |
Sumario: | In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetrahedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluorobenzene ring about its connecting C—C bond. In the crystal, pairs of intermolecular N—H⋯O(=P) hydrogen bonds form centrosymmetric dimers. |
---|