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N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide

In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetra­hedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0...

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Detalles Bibliográficos
Autores principales: Tarahhomi, Atekeh, Pourayoubi, Mehrdad, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201378/
https://www.ncbi.nlm.nih.gov/pubmed/22058773
http://dx.doi.org/10.1107/S1600536811036944
Descripción
Sumario:In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetra­hedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluoro­benzene ring about its connecting C—C bond. In the crystal, pairs of inter­molecular N—H⋯O(=P) hydrogen bonds form centrosymmetric dimers.