Cargando…
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide
In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetrahedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201378/ https://www.ncbi.nlm.nih.gov/pubmed/22058773 http://dx.doi.org/10.1107/S1600536811036944 |
_version_ | 1782214861010239488 |
---|---|
author | Tarahhomi, Atekeh Pourayoubi, Mehrdad Rheingold, Arnold L. Golen, James A. |
author_facet | Tarahhomi, Atekeh Pourayoubi, Mehrdad Rheingold, Arnold L. Golen, James A. |
author_sort | Tarahhomi, Atekeh |
collection | PubMed |
description | In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetrahedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluorobenzene ring about its connecting C—C bond. In the crystal, pairs of intermolecular N—H⋯O(=P) hydrogen bonds form centrosymmetric dimers. |
format | Online Article Text |
id | pubmed-3201378 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013782011-11-06 N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide Tarahhomi, Atekeh Pourayoubi, Mehrdad Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetrahedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluorobenzene ring about its connecting C—C bond. In the crystal, pairs of intermolecular N—H⋯O(=P) hydrogen bonds form centrosymmetric dimers. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201378/ /pubmed/22058773 http://dx.doi.org/10.1107/S1600536811036944 Text en © Tarahhomi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tarahhomi, Atekeh Pourayoubi, Mehrdad Rheingold, Arnold L. Golen, James A. N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide |
title |
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide |
title_full |
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide |
title_fullStr |
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide |
title_full_unstemmed |
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide |
title_short |
N,N,N′,N′-Tetraethyl-N′′-(2-fluorobenzoyl)phosphoric triamide |
title_sort | n,n,n′,n′-tetraethyl-n′′-(2-fluorobenzoyl)phosphoric triamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201378/ https://www.ncbi.nlm.nih.gov/pubmed/22058773 http://dx.doi.org/10.1107/S1600536811036944 |
work_keys_str_mv | AT tarahhomiatekeh nnnntetraethyln2fluorobenzoylphosphorictriamide AT pourayoubimehrdad nnnntetraethyln2fluorobenzoylphosphorictriamide AT rheingoldarnoldl nnnntetraethyln2fluorobenzoylphosphorictriamide AT golenjamesa nnnntetraethyln2fluorobenzoylphosphorictriamide |