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N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide

In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetra­hedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0...

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Autores principales: Tarahhomi, Atekeh, Pourayoubi, Mehrdad, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201378/
https://www.ncbi.nlm.nih.gov/pubmed/22058773
http://dx.doi.org/10.1107/S1600536811036944
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author Tarahhomi, Atekeh
Pourayoubi, Mehrdad
Rheingold, Arnold L.
Golen, James A.
author_facet Tarahhomi, Atekeh
Pourayoubi, Mehrdad
Rheingold, Arnold L.
Golen, James A.
author_sort Tarahhomi, Atekeh
collection PubMed
description In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetra­hedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluoro­benzene ring about its connecting C—C bond. In the crystal, pairs of inter­molecular N—H⋯O(=P) hydrogen bonds form centrosymmetric dimers.
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spelling pubmed-32013782011-11-06 N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide Tarahhomi, Atekeh Pourayoubi, Mehrdad Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(25)FN(3)O(2)P, the phosphoryl group is in an anti and syn orientation to the C=O and N—H groups, respectively. The P atom is in a distorted tetra­hedral environment. One of the ethyl groups is disordered over two sets of sites with refined occupancies of 0.755 (6) and 0.245 (6). In addition, the F atom was refined as disordered with occupancies fixed at 0.9 and 0.1. This disorder corresponds to a rotation of approximately 180° of the fluoro­benzene ring about its connecting C—C bond. In the crystal, pairs of inter­molecular N—H⋯O(=P) hydrogen bonds form centrosymmetric dimers. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201378/ /pubmed/22058773 http://dx.doi.org/10.1107/S1600536811036944 Text en © Tarahhomi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tarahhomi, Atekeh
Pourayoubi, Mehrdad
Rheingold, Arnold L.
Golen, James A.
N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide
title N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide
title_full N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide
title_fullStr N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide
title_full_unstemmed N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide
title_short N,N,N′,N′-Tetra­ethyl-N′′-(2-fluoro­benzo­yl)phospho­ric triamide
title_sort n,n,n′,n′-tetra­ethyl-n′′-(2-fluoro­benzo­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201378/
https://www.ncbi.nlm.nih.gov/pubmed/22058773
http://dx.doi.org/10.1107/S1600536811036944
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