1,7-Diethyl-4,10-diisopropyl­tetra­cene

The mol­ecule of the title compound, C(28)H(32), is located on a crystallographic inversion center. The ethyl groups are essentially coplanar with the tetra­cene ring, making a torsion angle of −0.4 (4)°. The isopropyl groups adopt an asymmetric conformation with their terminal methyl groups positio...

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Autores principales: Kitamura, Chitoshi, Kano, Hiroyuki, Kawase, Takeshi, Kobayashi, Takashi, Naito, Hiroyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201380/
https://www.ncbi.nlm.nih.gov/pubmed/22058757
http://dx.doi.org/10.1107/S1600536811036415
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author Kitamura, Chitoshi
Kano, Hiroyuki
Kawase, Takeshi
Kobayashi, Takashi
Naito, Hiroyoshi
author_facet Kitamura, Chitoshi
Kano, Hiroyuki
Kawase, Takeshi
Kobayashi, Takashi
Naito, Hiroyoshi
author_sort Kitamura, Chitoshi
collection PubMed
description The mol­ecule of the title compound, C(28)H(32), is located on a crystallographic inversion center. The ethyl groups are essentially coplanar with the tetra­cene ring, making a torsion angle of −0.4 (4)°. The isopropyl groups adopt an asymmetric conformation with their terminal methyl groups positioned on opposite sides of the tetra­cene plane [the Me—C—C—C torsion angles are −22.5 (4) and 100.9 (3)°]. In the crystal, the mol­ecules adopt an arrangement without significant π–π inter­actions along the stacking direction (y axis).
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spelling pubmed-32013802011-11-06 1,7-Diethyl-4,10-diisopropyl­tetra­cene Kitamura, Chitoshi Kano, Hiroyuki Kawase, Takeshi Kobayashi, Takashi Naito, Hiroyoshi Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(28)H(32), is located on a crystallographic inversion center. The ethyl groups are essentially coplanar with the tetra­cene ring, making a torsion angle of −0.4 (4)°. The isopropyl groups adopt an asymmetric conformation with their terminal methyl groups positioned on opposite sides of the tetra­cene plane [the Me—C—C—C torsion angles are −22.5 (4) and 100.9 (3)°]. In the crystal, the mol­ecules adopt an arrangement without significant π–π inter­actions along the stacking direction (y axis). International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201380/ /pubmed/22058757 http://dx.doi.org/10.1107/S1600536811036415 Text en © Kitamura et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kitamura, Chitoshi
Kano, Hiroyuki
Kawase, Takeshi
Kobayashi, Takashi
Naito, Hiroyoshi
1,7-Diethyl-4,10-diisopropyl­tetra­cene
title 1,7-Diethyl-4,10-diisopropyl­tetra­cene
title_full 1,7-Diethyl-4,10-diisopropyl­tetra­cene
title_fullStr 1,7-Diethyl-4,10-diisopropyl­tetra­cene
title_full_unstemmed 1,7-Diethyl-4,10-diisopropyl­tetra­cene
title_short 1,7-Diethyl-4,10-diisopropyl­tetra­cene
title_sort 1,7-diethyl-4,10-diisopropyl­tetra­cene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201380/
https://www.ncbi.nlm.nih.gov/pubmed/22058757
http://dx.doi.org/10.1107/S1600536811036415
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AT naitohiroyoshi 17diethyl410diisopropyltetracene

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