(3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one

In the title compound, C(27)H(25)NO, the piperidine ring adopts an envelope conformation with the N atom at the flap position. The two benzylidene-benzene rings are oriented at a dihedral angle of 8.5 (1)°. In the crystal, the mol­ecules are linked into centrosymmetric dimers by pairs of inter­molec...

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Autores principales: Ali, Mohamed Ashraf, Choon, Tan Soo, Almansour, Abdulrahman I., Shahani, Tara, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201386/
https://www.ncbi.nlm.nih.gov/pubmed/22058753
http://dx.doi.org/10.1107/S1600536811035744
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author Ali, Mohamed Ashraf
Choon, Tan Soo
Almansour, Abdulrahman I.
Shahani, Tara
Fun, Hoong-Kun
author_facet Ali, Mohamed Ashraf
Choon, Tan Soo
Almansour, Abdulrahman I.
Shahani, Tara
Fun, Hoong-Kun
author_sort Ali, Mohamed Ashraf
collection PubMed
description In the title compound, C(27)H(25)NO, the piperidine ring adopts an envelope conformation with the N atom at the flap position. The two benzylidene-benzene rings are oriented at a dihedral angle of 8.5 (1)°. In the crystal, the mol­ecules are linked into centrosymmetric dimers by pairs of inter­molecular C—H⋯O hydrogen bonds. The dimers are connected via C—H⋯π inter­actions involving the phenyl rings.
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spelling pubmed-32013862011-11-06 (3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one Ali, Mohamed Ashraf Choon, Tan Soo Almansour, Abdulrahman I. Shahani, Tara Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(25)NO, the piperidine ring adopts an envelope conformation with the N atom at the flap position. The two benzylidene-benzene rings are oriented at a dihedral angle of 8.5 (1)°. In the crystal, the mol­ecules are linked into centrosymmetric dimers by pairs of inter­molecular C—H⋯O hydrogen bonds. The dimers are connected via C—H⋯π inter­actions involving the phenyl rings. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201386/ /pubmed/22058753 http://dx.doi.org/10.1107/S1600536811035744 Text en © Ali et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ali, Mohamed Ashraf
Choon, Tan Soo
Almansour, Abdulrahman I.
Shahani, Tara
Fun, Hoong-Kun
(3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one
title (3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one
title_full (3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one
title_fullStr (3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one
title_full_unstemmed (3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one
title_short (3E,5E)-3,5-Dibenzyl­idene-1-phenethyl­piperidin-4-one
title_sort (3e,5e)-3,5-dibenzyl­idene-1-phenethyl­piperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201386/
https://www.ncbi.nlm.nih.gov/pubmed/22058753
http://dx.doi.org/10.1107/S1600536811035744
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