2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate

In the title salt, C(6)H(10)N(3)O(2) (+)·C(7)H(7)O(3)S(−), the 2-amino-4,6-dimeth­oxy­pyrimidinium cation inter­acts with the sulfonate group of the p-toluene­sulfonate anion via a pair of N—H⋯O hydrogen bonds, forming a cyclic hydrogen-bonded R (2) (2)(8) motif, which in the crystal is linked by fu...

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Detalles Bibliográficos
Autores principales: Gomathi, Sundaramoorthy, Muthiah, Packianathan Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201388/
https://www.ncbi.nlm.nih.gov/pubmed/22064770
http://dx.doi.org/10.1107/S160053681103755X
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author Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
author_facet Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
author_sort Gomathi, Sundaramoorthy
collection PubMed
description In the title salt, C(6)H(10)N(3)O(2) (+)·C(7)H(7)O(3)S(−), the 2-amino-4,6-dimeth­oxy­pyrimidinium cation inter­acts with the sulfonate group of the p-toluene­sulfonate anion via a pair of N—H⋯O hydrogen bonds, forming a cyclic hydrogen-bonded R (2) (2)(8) motif, which in the crystal is linked by further intemolecular N—H⋯O hydrogen bonds, forming supra­molecular chains along the c axis. Furthermore, neighboring chains are inter­linked via weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming layers.
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spelling pubmed-32013882011-11-06 2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate Gomathi, Sundaramoorthy Muthiah, Packianathan Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(10)N(3)O(2) (+)·C(7)H(7)O(3)S(−), the 2-amino-4,6-dimeth­oxy­pyrimidinium cation inter­acts with the sulfonate group of the p-toluene­sulfonate anion via a pair of N—H⋯O hydrogen bonds, forming a cyclic hydrogen-bonded R (2) (2)(8) motif, which in the crystal is linked by further intemolecular N—H⋯O hydrogen bonds, forming supra­molecular chains along the c axis. Furthermore, neighboring chains are inter­linked via weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming layers. International Union of Crystallography 2011-09-17 /pmc/articles/PMC3201388/ /pubmed/22064770 http://dx.doi.org/10.1107/S160053681103755X Text en © Gomathi and Muthiah 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gomathi, Sundaramoorthy
Muthiah, Packianathan Thomas
2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
title 2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
title_full 2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
title_fullStr 2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
title_full_unstemmed 2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
title_short 2-Amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
title_sort 2-amino-4,6-dimeth­oxy­pyrimidin-1-ium p-toluene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201388/
https://www.ncbi.nlm.nih.gov/pubmed/22064770
http://dx.doi.org/10.1107/S160053681103755X
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