Potassium ditin(IV) tris­[phosphate(V)], KSn(2)(PO(4))(3)

The title compound, KSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates with the space group R [Image: see text]. Its structure is constructed by very regular [with P—O distances ranging from 1.513 (6) to 1.522 (6) Å] PO(4) tetra­hedra and SnO(6) octa­hedra on the 3. axis, which are l...

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Detalles Bibliográficos
Autor principal: Zhang, Hui Ju
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201389/
https://www.ncbi.nlm.nih.gov/pubmed/22064788
http://dx.doi.org/10.1107/S1600536811035604
Descripción
Sumario:The title compound, KSn(2)(PO(4))(3), belongs to the NASICON-type family of phosphates with the space group R [Image: see text]. Its structure is constructed by very regular [with P—O distances ranging from 1.513 (6) to 1.522 (6) Å] PO(4) tetra­hedra and SnO(6) octa­hedra on the 3. axis, which are linked by O atoms, forming an [Sn(2)(PO(4))(3)] framework. The K atoms occupy the [Image: see text]. axis sites and are located in the voids of this arrangement. The crystal studied was a merohedral twin with twin law (010 100 00[Image: see text]) and a component ratio of 0.580 (7):0.420 (7).

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