1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide

The title compound C(14)H(29)N(4) (+)·I(−) salt, was obtained by the reaction of cage adamanzane-type aminal 1,3,6,8-tetra­aza­tricyclo­[4.3.1.1(3,8)]undecane with heptyl iodide. In the cation, the bond lengths and angles are within normal ranges, except for one N—C(ring) bond distance of 1.542 (3) ...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Sadat-Bernal, John, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201392/
https://www.ncbi.nlm.nih.gov/pubmed/22064969
http://dx.doi.org/10.1107/S1600536811036403
Descripción
Sumario:The title compound C(14)H(29)N(4) (+)·I(−) salt, was obtained by the reaction of cage adamanzane-type aminal 1,3,6,8-tetra­aza­tricyclo­[4.3.1.1(3,8)]undecane with heptyl iodide. In the cation, the bond lengths and angles are within normal ranges, except for one N—C(ring) bond distance of 1.542 (3) Å, which is unexpectedly long compared with related compounds. In the crystal, ions are linked through C—H⋯I hydrogen bonds. The crystal studied was a non-merohedral twin with a minor twin domain of 6.56 (5)%.

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