1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide

The title compound C(14)H(29)N(4) (+)·I(−) salt, was obtained by the reaction of cage adamanzane-type aminal 1,3,6,8-tetra­aza­tricyclo­[4.3.1.1(3,8)]undecane with heptyl iodide. In the cation, the bond lengths and angles are within normal ranges, except for one N—C(ring) bond distance of 1.542 (3) ...

Descripción completa

Detalles Bibliográficos
Autores principales: Rivera, Augusto, Sadat-Bernal, John, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201392/
https://www.ncbi.nlm.nih.gov/pubmed/22064969
http://dx.doi.org/10.1107/S1600536811036403
_version_ 1782214864153870336
author Rivera, Augusto
Sadat-Bernal, John
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
author_facet Rivera, Augusto
Sadat-Bernal, John
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
author_sort Rivera, Augusto
collection PubMed
description The title compound C(14)H(29)N(4) (+)·I(−) salt, was obtained by the reaction of cage adamanzane-type aminal 1,3,6,8-tetra­aza­tricyclo­[4.3.1.1(3,8)]undecane with heptyl iodide. In the cation, the bond lengths and angles are within normal ranges, except for one N—C(ring) bond distance of 1.542 (3) Å, which is unexpectedly long compared with related compounds. In the crystal, ions are linked through C—H⋯I hydrogen bonds. The crystal studied was a non-merohedral twin with a minor twin domain of 6.56 (5)%.
format Online
Article
Text
id pubmed-3201392
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32013922011-11-06 1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide Rivera, Augusto Sadat-Bernal, John Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound C(14)H(29)N(4) (+)·I(−) salt, was obtained by the reaction of cage adamanzane-type aminal 1,3,6,8-tetra­aza­tricyclo­[4.3.1.1(3,8)]undecane with heptyl iodide. In the cation, the bond lengths and angles are within normal ranges, except for one N—C(ring) bond distance of 1.542 (3) Å, which is unexpectedly long compared with related compounds. In the crystal, ions are linked through C—H⋯I hydrogen bonds. The crystal studied was a non-merohedral twin with a minor twin domain of 6.56 (5)%. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201392/ /pubmed/22064969 http://dx.doi.org/10.1107/S1600536811036403 Text en © Rivera et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rivera, Augusto
Sadat-Bernal, John
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
title 1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
title_full 1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
title_fullStr 1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
title_full_unstemmed 1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
title_short 1-Heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
title_sort 1-heptyl-1,3,6,8-tetraaza­tricyclo­[4.3.1.1(3,8)]undecan-1-ium iodide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201392/
https://www.ncbi.nlm.nih.gov/pubmed/22064969
http://dx.doi.org/10.1107/S1600536811036403
work_keys_str_mv AT riveraaugusto 1heptyl1368tetraazatricyclo431138undecan1iumiodide
AT sadatbernaljohn 1heptyl1368tetraazatricyclo431138undecan1iumiodide
AT riosmottajaime 1heptyl1368tetraazatricyclo431138undecan1iumiodide
AT fejfarovakarla 1heptyl1368tetraazatricyclo431138undecan1iumiodide
AT dusekmichal 1heptyl1368tetraazatricyclo431138undecan1iumiodide

Ejemplares similares