Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)

The Hg(II) atom in the title complex, [HgI(2)(C(12)H(6)N(2)O(2))], is tetra­hedrally coordinated by the N atoms of the chelating 1,10-phenanthroline-5,6-dione ligand and two I atoms. The range of tetra­hedral angles is broad, viz. 68.94 (17)° for the chelate angle to a wide 132.627 (15)° for the I—H...

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Autores principales: Ghaemi, Akbar, Shojaiean, Rezvan, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201394/
https://www.ncbi.nlm.nih.gov/pubmed/22065119
http://dx.doi.org/10.1107/S1600536811038748
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author Ghaemi, Akbar
Shojaiean, Rezvan
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Ghaemi, Akbar
Shojaiean, Rezvan
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Ghaemi, Akbar
collection PubMed
description The Hg(II) atom in the title complex, [HgI(2)(C(12)H(6)N(2)O(2))], is tetra­hedrally coordinated by the N atoms of the chelating 1,10-phenanthroline-5,6-dione ligand and two I atoms. The range of tetra­hedral angles is broad, viz. 68.94 (17)° for the chelate angle to a wide 132.627 (15)° for the I—Hg—I angle. The ligand mol­ecule is non-planar with the O atoms lying 0.422 (5) and −0.325 (5) Å out of the plane through the remaining atoms [r.m.s. deviation = 0.068 Å]. Mol­ecules are consolidated in the crystal packing by C—H⋯O inter­actions.
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spelling pubmed-32013942011-11-06 Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II) Ghaemi, Akbar Shojaiean, Rezvan Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg(II) atom in the title complex, [HgI(2)(C(12)H(6)N(2)O(2))], is tetra­hedrally coordinated by the N atoms of the chelating 1,10-phenanthroline-5,6-dione ligand and two I atoms. The range of tetra­hedral angles is broad, viz. 68.94 (17)° for the chelate angle to a wide 132.627 (15)° for the I—Hg—I angle. The ligand mol­ecule is non-planar with the O atoms lying 0.422 (5) and −0.325 (5) Å out of the plane through the remaining atoms [r.m.s. deviation = 0.068 Å]. Mol­ecules are consolidated in the crystal packing by C—H⋯O inter­actions. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201394/ /pubmed/22065119 http://dx.doi.org/10.1107/S1600536811038748 Text en © Ghaemi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ghaemi, Akbar
Shojaiean, Rezvan
Ng, Seik Weng
Tiekink, Edward R. T.
Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_full Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_fullStr Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_full_unstemmed Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_short Diiodido(1,10-phenanthroline-5,6-dione-κ(2) N,N′)mercury(II)
title_sort diiodido(1,10-phenanthroline-5,6-dione-κ(2) n,n′)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201394/
https://www.ncbi.nlm.nih.gov/pubmed/22065119
http://dx.doi.org/10.1107/S1600536811038748
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