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Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)

In the title diorganotin dicarboxyl­ate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxyl­ate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn...

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Detalles Bibliográficos
Autores principales: Basu Baul, Tushar S., Paul, Anup, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201396/
https://www.ncbi.nlm.nih.gov/pubmed/22065466
http://dx.doi.org/10.1107/S1600536811036543
Descripción
Sumario:In the title diorganotin dicarboxyl­ate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxyl­ate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn—C bonds disposed over the weaker Sn—O bonds. Within each carboxyl­ate ligand, the hydroxyl-H atom forms bifurcated O—H⋯(O,N) hydrogen bonds with carboxyl­ate-O and azo-N atoms. The dihedral angles between the benzene rings in the two ligands are 10.44 (11) and 34.24 (11)°. In the crystal, centrosymmetric dimers are formed through pairs of Sn⋯O inter­actions [2.8802 (16) Å], and the dimers are linked into supra­molecular layers in the ac plane by C—H⋯π inter­actions.