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Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV)
In the title diorganotin dicarboxylate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxylate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201396/ https://www.ncbi.nlm.nih.gov/pubmed/22065466 http://dx.doi.org/10.1107/S1600536811036543 |
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author | Basu Baul, Tushar S. Paul, Anup Tiekink, Edward R. T. |
author_facet | Basu Baul, Tushar S. Paul, Anup Tiekink, Edward R. T. |
author_sort | Basu Baul, Tushar S. |
collection | PubMed |
description | In the title diorganotin dicarboxylate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxylate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn—C bonds disposed over the weaker Sn—O bonds. Within each carboxylate ligand, the hydroxyl-H atom forms bifurcated O—H⋯(O,N) hydrogen bonds with carboxylate-O and azo-N atoms. The dihedral angles between the benzene rings in the two ligands are 10.44 (11) and 34.24 (11)°. In the crystal, centrosymmetric dimers are formed through pairs of Sn⋯O interactions [2.8802 (16) Å], and the dimers are linked into supramolecular layers in the ac plane by C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3201396 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32013962011-11-06 Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) Basu Baul, Tushar S. Paul, Anup Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title diorganotin dicarboxylate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxylate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn—C bonds disposed over the weaker Sn—O bonds. Within each carboxylate ligand, the hydroxyl-H atom forms bifurcated O—H⋯(O,N) hydrogen bonds with carboxylate-O and azo-N atoms. The dihedral angles between the benzene rings in the two ligands are 10.44 (11) and 34.24 (11)°. In the crystal, centrosymmetric dimers are formed through pairs of Sn⋯O interactions [2.8802 (16) Å], and the dimers are linked into supramolecular layers in the ac plane by C—H⋯π interactions. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201396/ /pubmed/22065466 http://dx.doi.org/10.1107/S1600536811036543 Text en © Basu Baul et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Basu Baul, Tushar S. Paul, Anup Tiekink, Edward R. T. Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) |
title | Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) |
title_full | Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) |
title_fullStr | Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) |
title_full_unstemmed | Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) |
title_short | Bis{2-[(E)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(IV) |
title_sort | bis{2-[(e)-(5-tert-butyl-2-hydroxyphenyl)diazenyl]benzoato}dimethyltin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201396/ https://www.ncbi.nlm.nih.gov/pubmed/22065466 http://dx.doi.org/10.1107/S1600536811036543 |
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