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Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)

In the title diorganotin dicarboxyl­ate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxyl­ate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn...

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Autores principales: Basu Baul, Tushar S., Paul, Anup, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201396/
https://www.ncbi.nlm.nih.gov/pubmed/22065466
http://dx.doi.org/10.1107/S1600536811036543
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author Basu Baul, Tushar S.
Paul, Anup
Tiekink, Edward R. T.
author_facet Basu Baul, Tushar S.
Paul, Anup
Tiekink, Edward R. T.
author_sort Basu Baul, Tushar S.
collection PubMed
description In the title diorganotin dicarboxyl­ate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxyl­ate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn—C bonds disposed over the weaker Sn—O bonds. Within each carboxyl­ate ligand, the hydroxyl-H atom forms bifurcated O—H⋯(O,N) hydrogen bonds with carboxyl­ate-O and azo-N atoms. The dihedral angles between the benzene rings in the two ligands are 10.44 (11) and 34.24 (11)°. In the crystal, centrosymmetric dimers are formed through pairs of Sn⋯O inter­actions [2.8802 (16) Å], and the dimers are linked into supra­molecular layers in the ac plane by C—H⋯π inter­actions.
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spelling pubmed-32013962011-11-06 Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV) Basu Baul, Tushar S. Paul, Anup Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title diorganotin dicarboxyl­ate, [Sn(CH(3))(2)(C(17)H(17)N(2)O(3))(2)], the tin(IV) atom is six-coordinated by four O atoms derived from asymmetrically coordinating carboxyl­ate ligands, and two methyl-C atoms. The resulting C(2)O(4) donor set defines a skew-trapezoidal bipyramid with the Sn—C bonds disposed over the weaker Sn—O bonds. Within each carboxyl­ate ligand, the hydroxyl-H atom forms bifurcated O—H⋯(O,N) hydrogen bonds with carboxyl­ate-O and azo-N atoms. The dihedral angles between the benzene rings in the two ligands are 10.44 (11) and 34.24 (11)°. In the crystal, centrosymmetric dimers are formed through pairs of Sn⋯O inter­actions [2.8802 (16) Å], and the dimers are linked into supra­molecular layers in the ac plane by C—H⋯π inter­actions. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201396/ /pubmed/22065466 http://dx.doi.org/10.1107/S1600536811036543 Text en © Basu Baul et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Basu Baul, Tushar S.
Paul, Anup
Tiekink, Edward R. T.
Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)
title Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)
title_full Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)
title_fullStr Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)
title_full_unstemmed Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)
title_short Bis{2-[(E)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(IV)
title_sort bis{2-[(e)-(5-tert-butyl-2-hy­droxy­phen­yl)diazen­yl]benzoato}dimethyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201396/
https://www.ncbi.nlm.nih.gov/pubmed/22065466
http://dx.doi.org/10.1107/S1600536811036543
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AT tiekinkedwardrt bis2e5tertbutyl2hydroxyphenyldiazenylbenzoatodimethyltiniv