Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate

The title compound, [PdCl(2)(C(23)H(23)NO)]·CH(3)OH, was obtained by the reaction of 1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hy­droxy­limine part of the bid...

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Autores principales: Liu, Feng-Shou, Huang, Ying-Tang, Shen, Dong-Sheng, Yao, Hua-Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201399/
https://www.ncbi.nlm.nih.gov/pubmed/22065642
http://dx.doi.org/10.1107/S1600536811037986
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author Liu, Feng-Shou
Huang, Ying-Tang
Shen, Dong-Sheng
Yao, Hua-Gang
author_facet Liu, Feng-Shou
Huang, Ying-Tang
Shen, Dong-Sheng
Yao, Hua-Gang
author_sort Liu, Feng-Shou
collection PubMed
description The title compound, [PdCl(2)(C(23)H(23)NO)]·CH(3)OH, was obtained by the reaction of 1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hy­droxy­limine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex mol­ecule and the uncoordinated methanol mol­ecule are connected via an O—H⋯O hydrogen bond.
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spelling pubmed-32013992011-11-06 Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate Liu, Feng-Shou Huang, Ying-Tang Shen, Dong-Sheng Yao, Hua-Gang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [PdCl(2)(C(23)H(23)NO)]·CH(3)OH, was obtained by the reaction of 1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hy­droxy­limine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex mol­ecule and the uncoordinated methanol mol­ecule are connected via an O—H⋯O hydrogen bond. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201399/ /pubmed/22065642 http://dx.doi.org/10.1107/S1600536811037986 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Feng-Shou
Huang, Ying-Tang
Shen, Dong-Sheng
Yao, Hua-Gang
Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate
title Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate
title_full Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate
title_fullStr Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate
title_full_unstemmed Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate
title_short Dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) N,O]palladium(II) methanol monosolvate
title_sort dichlorido[1-(2,6-dimethyl­phenyl­imino)-1,2-diphenyl­propan-2-ol-κ(2) n,o]palladium(ii) methanol monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201399/
https://www.ncbi.nlm.nih.gov/pubmed/22065642
http://dx.doi.org/10.1107/S1600536811037986
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