Dicaesium diaqua­bis­(methyl­ene­diphospho­nato-κ(2) O,O′)cobaltate(II)

The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl­enediphospho­nate ligand and one water mol­ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystall...

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Detalles Bibliográficos
Autores principales: van Merwe, Kina, Visser, Hendrik G., Venter, Johan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201400/
https://www.ncbi.nlm.nih.gov/pubmed/22065711
http://dx.doi.org/10.1107/S1600536811035355
Descripción
Sumario:The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl­enediphospho­nate ligand and one water mol­ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octa­hedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H⋯O hydrogen bonds.

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