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Dicaesium diaquabis(methylenediphosphonato-κ(2) O,O′)cobaltate(II)
The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystall...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201400/ https://www.ncbi.nlm.nih.gov/pubmed/22065711 http://dx.doi.org/10.1107/S1600536811035355 |
| _version_ | 1782214865963712512 |
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| author | van Merwe, Kina Visser, Hendrik G. Venter, Johan A. |
| author_facet | van Merwe, Kina Visser, Hendrik G. Venter, Johan A. |
| author_sort | van Merwe, Kina |
| collection | PubMed |
| description | The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H⋯O hydrogen bonds. |
| format | Online Article Text |
| id | pubmed-3201400 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014002011-11-06 Dicaesium diaquabis(methylenediphosphonato-κ(2) O,O′)cobaltate(II) van Merwe, Kina Visser, Hendrik G. Venter, Johan A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methylenediphosphonate ligand and one water molecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octahedrally coordinated by six O atoms with Cs—O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O—H⋯O hydrogen bonds. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201400/ /pubmed/22065711 http://dx.doi.org/10.1107/S1600536811035355 Text en © Merwe et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers van Merwe, Kina Visser, Hendrik G. Venter, Johan A. Dicaesium diaquabis(methylenediphosphonato-κ(2) O,O′)cobaltate(II) |
| title | Dicaesium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_full | Dicaesium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_fullStr | Dicaesium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_full_unstemmed | Dicaesium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_short | Dicaesium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_sort | dicaesium diaquabis(methylenediphosphonato-κ(2)
o,o′)cobaltate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201400/ https://www.ncbi.nlm.nih.gov/pubmed/22065711 http://dx.doi.org/10.1107/S1600536811035355 |
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