Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)

The structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](−) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (−), consists of discrete essentially isolated ions. Both the cation and the anion lie on...

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Detalles Bibliográficos
Autores principales: De Lorentiis, Lucio, Graiff, Claudia, Predieri, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201402/
https://www.ncbi.nlm.nih.gov/pubmed/22065826
http://dx.doi.org/10.1107/S1600536811035422
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author De Lorentiis, Lucio
Graiff, Claudia
Predieri, Giovanni
author_facet De Lorentiis, Lucio
Graiff, Claudia
Predieri, Giovanni
author_sort De Lorentiis, Lucio
collection PubMed
description The structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](−) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (−), consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the Sn(IV) atom in the anion. In the crystal, the ions inter­act only through a weak inter­action between the Cl atom of the anion and an H atom of a phenyl ring of the cation.
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spelling pubmed-32014022011-11-06 Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV) De Lorentiis, Lucio Graiff, Claudia Predieri, Giovanni Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Ph(3)P=N=PPh(3)](+)[Ph(3)SnCl(2)](−) or (C(36)H(30)NP(2))[Sn(C(6)H(5))(3)Cl(2)], obtained as a by product of the reaction between Ph(3)SnCl and [Ph(3)P=N=PPh(3)](+)·HSeO(3) (−), consists of discrete essentially isolated ions. Both the cation and the anion lie on twofold axes which pass through the central N atom in the cation and through the Sn(IV) atom in the anion. In the crystal, the ions inter­act only through a weak inter­action between the Cl atom of the anion and an H atom of a phenyl ring of the cation. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201402/ /pubmed/22065826 http://dx.doi.org/10.1107/S1600536811035422 Text en © De Lorentiis et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
De Lorentiis, Lucio
Graiff, Claudia
Predieri, Giovanni
Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)
title Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)
title_full Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)
title_fullStr Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)
title_full_unstemmed Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)
title_short Bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(IV)
title_sort bis(triphenyl­phosphanyl­idene)iminium dichloridotriphenyl­stannate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201402/
https://www.ncbi.nlm.nih.gov/pubmed/22065826
http://dx.doi.org/10.1107/S1600536811035422
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