2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine

In the title mol­ecule, C(23)H(19)ClN(2), the heterocyclic ring adopts a screw-boat conformation, with all substituents equatorial. The benzene ring at position 2 makes dihedral angles of 77.88 (12) and 76.31 (12)° with the phenyl rings at positions 5 and 6, respectively. The dihedral angle between...

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Autores principales: Anuradha, N., Chitra, S., Thiruvalluvar, A., Pandiarajan, K., Butcher, R. J., Jasinski, J. P., Golen, J. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201404/
https://www.ncbi.nlm.nih.gov/pubmed/22065837
http://dx.doi.org/10.1107/S1600536811036336
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author Anuradha, N.
Chitra, S.
Thiruvalluvar, A.
Pandiarajan, K.
Butcher, R. J.
Jasinski, J. P.
Golen, J. A.
author_facet Anuradha, N.
Chitra, S.
Thiruvalluvar, A.
Pandiarajan, K.
Butcher, R. J.
Jasinski, J. P.
Golen, J. A.
author_sort Anuradha, N.
collection PubMed
description In the title mol­ecule, C(23)H(19)ClN(2), the heterocyclic ring adopts a screw-boat conformation, with all substituents equatorial. The benzene ring at position 2 makes dihedral angles of 77.88 (12) and 76.31 (12)° with the phenyl rings at positions 5 and 6, respectively. The dihedral angle between the phenyl rings at positions 5 and 6 is 70.05 (10)°. The Cl atom is disordered over two positions with occupancy factors of 0.946 (5) and 0.054 (5). In the crystal, C—H⋯π inter­actions are found.
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spelling pubmed-32014042011-11-06 2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine Anuradha, N. Chitra, S. Thiruvalluvar, A. Pandiarajan, K. Butcher, R. J. Jasinski, J. P. Golen, J. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(23)H(19)ClN(2), the heterocyclic ring adopts a screw-boat conformation, with all substituents equatorial. The benzene ring at position 2 makes dihedral angles of 77.88 (12) and 76.31 (12)° with the phenyl rings at positions 5 and 6, respectively. The dihedral angle between the phenyl rings at positions 5 and 6 is 70.05 (10)°. The Cl atom is disordered over two positions with occupancy factors of 0.946 (5) and 0.054 (5). In the crystal, C—H⋯π inter­actions are found. International Union of Crystallography 2011-09-14 /pmc/articles/PMC3201404/ /pubmed/22065837 http://dx.doi.org/10.1107/S1600536811036336 Text en © Anuradha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anuradha, N.
Chitra, S.
Thiruvalluvar, A.
Pandiarajan, K.
Butcher, R. J.
Jasinski, J. P.
Golen, J. A.
2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
title 2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
title_full 2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
title_fullStr 2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
title_full_unstemmed 2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
title_short 2-(2-Chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
title_sort 2-(2-chloro­phen­yl)-3-methyl-5,6-diphenyl-2,3-dihydro­pyrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201404/
https://www.ncbi.nlm.nih.gov/pubmed/22065837
http://dx.doi.org/10.1107/S1600536811036336
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