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Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4) N,O,O′,N′]chloridocadmium}
In centrosymmetric dinuclear title compound, [Cd(2)Cl(4)(C(18)H(16)N(2)O(2))(2)], the Cd(II) atom is seven-coordinated in a pentagonal–bipyramidal environment defined by two N atoms and two O atoms from one ligand and three Cl(−) anions, two of which are bridging. A π–π interaction between adjacen...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201405/ https://www.ncbi.nlm.nih.gov/pubmed/22064381 http://dx.doi.org/10.1107/S1600536811037858 |
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| author | Gao, Jin-Sheng Yu, Ying-Hui Liu, Ying Hou, Guang-Feng |
| author_facet | Gao, Jin-Sheng Yu, Ying-Hui Liu, Ying Hou, Guang-Feng |
| author_sort | Gao, Jin-Sheng |
| collection | PubMed |
| description | In centrosymmetric dinuclear title compound, [Cd(2)Cl(4)(C(18)H(16)N(2)O(2))(2)], the Cd(II) atom is seven-coordinated in a pentagonal–bipyramidal environment defined by two N atoms and two O atoms from one ligand and three Cl(−) anions, two of which are bridging. A π–π interaction between adjacent pyridine rings [centroid–centroid distance = 3.773 (1) Å] further stablizes the dimer. |
| format | Online Article Text |
| id | pubmed-3201405 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32014052011-11-06 Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4) N,O,O′,N′]chloridocadmium} Gao, Jin-Sheng Yu, Ying-Hui Liu, Ying Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In centrosymmetric dinuclear title compound, [Cd(2)Cl(4)(C(18)H(16)N(2)O(2))(2)], the Cd(II) atom is seven-coordinated in a pentagonal–bipyramidal environment defined by two N atoms and two O atoms from one ligand and three Cl(−) anions, two of which are bridging. A π–π interaction between adjacent pyridine rings [centroid–centroid distance = 3.773 (1) Å] further stablizes the dimer. International Union of Crystallography 2011-09-30 /pmc/articles/PMC3201405/ /pubmed/22064381 http://dx.doi.org/10.1107/S1600536811037858 Text en © Gao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Jin-Sheng Yu, Ying-Hui Liu, Ying Hou, Guang-Feng Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4) N,O,O′,N′]chloridocadmium} |
| title | Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]chloridocadmium} |
| title_full | Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]chloridocadmium} |
| title_fullStr | Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]chloridocadmium} |
| title_full_unstemmed | Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]chloridocadmium} |
| title_short | Di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
N,O,O′,N′]chloridocadmium} |
| title_sort | di-μ-chlorido-bis{[1,2-bis(pyridin-2-ylmethoxy)benzene-κ(4)
n,o,o′,n′]chloridocadmium} |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3201405/ https://www.ncbi.nlm.nih.gov/pubmed/22064381 http://dx.doi.org/10.1107/S1600536811037858 |
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